DICHLOROISOPROPYLPHOSPHINE

Base Information

• Chemical Name: DICHLOROISOPROPYLPHOSPHINE
• CAS No.: 25235-15-8
• Molecular Formula: C3H7 Cl2 P
• Molecular Weight: 144.968
• Hs Code.: 2903199000
• Mol file: 25235-15-8.mol

Synonyms:Phosphonousdichloride, (1-methylethyl)- (9CI); Phosphonous dichloride, isopropyl-(6CI,7CI,8CI); (1-Methylethyl)phosphonous dichloride;Dichloroisopropylphosphine; Isopropyldichlorophosphine; Isopropylphosphonousdichloride; Isopropylphosphorus dichloride

Chemical Property of DICHLOROISOPROPYLPHOSPHINE

Chemical Property:

• Vapor Pressure: 12.2mmHg at 25°C
• Refractive Index: n20/D 1.489(lit.)
• Boiling Point: 129.9°C at 760 mmHg
• Flash Point: 113 °F
• PSA: 13.59000
• Density: 1.176 g/mL at 25 °C(lit.)
• LogP: 3.18430

Purity/Quality:

99% ^*data from raw suppliers

Dichloroisopropylphosphine 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 10-14-34
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DICHLOROISOPROPYLPHOSPHINE

There total 8 articles about DICHLOROISOPROPYLPHOSPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

C3H7Cl3P(1+)*AlCl4(1-) → dichloroisopropylphosphine (25235-15-8) + isopropylphosphonic dichloride (1498-46-0)

Guidance literature:

With triphenylphosphine; for 2.5h; under 2 Torr; further phosphines or phosphites;

Reference yield: 65.0%

isopropylmagnesium chloride (1068-55-9) → dichloroisopropylphosphine (25235-15-8)

Guidance literature:

With phosphorus trichloride; In diethyl ether; for 2h; Heating;

DOI:10.1139/v96-244

Reference yield: 37.0%

C3H7Cl3P(1+)*AlCl4(1-) → dichloroisopropylphosphine (25235-15-8)

Guidance literature:

With butyltriethylammonium iodide; at 80 ℃; for 2h; in a vacuum;

upstream raw materials:

triisopropylaluminium

diisopropylmercury

diisopropyl cadmium

isopropylmagnesium chloride

Downstream raw materials:

(1-methylethyl)thioxophosphonic dichloride

Chlorodiisopropylphosphane

isopropylphosphonic dichloride

1,5,9-Triisopropyl-3,7-bis(4-trifluormethylphenyl)2,4,6,8-tetraaza-1λ⁵,5λ⁵,9-triphosphabicyclo<3.3.1>nona-1,3,5,7-tetraen