[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂

Base Information

Chemical Name:[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂
CAS No.:293764-38-2
Molecular Formula:C₂₇H₃₃Cl₂N₃Zr
Molecular Weight:561.709
Hs Code.:

[C<sub>5</sub>H<sub>4</sub>NC(CH<sub>3</sub>)(CH<sub>2</sub>NC<sub>6</sub>H<sub>2</sub>(CH<sub>3</sub>)3)2]ZrCl<sub>2</sub>

Synonyms:[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂

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Chemical Property of [C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂

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Technology Process of [C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂

There total 1 articles about [C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 75-77-4
chloro-trimethyl-silane

: 293764-36-0
[(N(CH₃)2)2Zr(C₅H₄NC(CH₃)(CH₂N(mesityl))2)]

: 293764-38-2
[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂

Guidance literature:: In diethyl ether; N2; addn. of silane to a soln. of Zrcomplex in diethyl ether, stirring at room temp. for 1 h; filtration, washing the solid with pentane three times, drying in vac. for 4 h; elem. anal.;
DOI:10.1021/om0207055

Reference yield: 92.0%

: 293764-38-2
[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂

: 926-62-5
isobutylmagnesium bromide

: 293764-42-8
[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]Zr(i-butyl)2

Guidance literature:: In diethyl ether; N2, absence of light; cooling of ether suspn. of Zr complex to -30°C, addn. of 2 equivs. of Grignard reagent as 2.0 M etehr soln. to the cold suspn., stirring at room temp. for 10 min until the suspn. is clear; addn. of dioxane, filtering through Celite, removal of solvent in vac.; elem. anal.;
DOI:10.1021/om0207055

Reference yield: 83.0%

: 293764-38-2
[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]ZrCl₂

: 6921-34-2
benzylmagnesium chloride

: 486413-17-6
[C₅H₄NC(CH₃)(CH₂NC₆H₂(CH₃)3)2]Zr(benzyl)2

Guidance literature:: In diethyl ether; N2; cooling of ether suspn. of Zr complex to -30°C, addn. of 2 equivs. of Grignard reagent as 1.0 M ether soln., stirring at room temp. for 15 min, until the suspn. becomes clear; addn. of dioxane, filtering through Celite, reduction of solvent to 5 ml, crystn. at -30°C for 1 d; elem. anal.;
DOI:10.1021/om0207055