(E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

Base Information

Chemical Name:(E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine
CAS No.:1381772-20-8
Molecular Formula:C₂₅H₂₇N₃O₃
Molecular Weight:417.508
Hs Code.:

Synonyms:(E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

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Technology Process of (E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

There total 4 articles about (E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1381772-03-7
1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-one

: 539-44-6
N-4-methylphenylhydrazine

: 1381772-20-8
(E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

: 1381772-24-2
(Z)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

Guidance literature:: In dichloromethane; for 17h; Molecular sieve; Inert atmosphere; Reflux;
DOI:10.1021/ja303054c

Reference yield:

: 20401-88-1
3-(4-methoxyphenyl)propional

: 1381772-20-8
(E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

: 1381772-24-2
(Z)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

Guidance literature:: Multi-step reaction with 3 steps

1: diethyl ether / 1 h / 0 °C / Inert atmosphere

2: palladium diacetate; triethylamine / acetonitrile / 17 h / Reflux; Inert atmosphere

3: dichloromethane / 17 h / Molecular sieve; Inert atmosphere; Reflux

With palladium diacetate; triethylamine; In diethyl ether; dichloromethane; acetonitrile; 2: Heck reaction;
DOI:10.1021/ja303054c

Reference yield:

: 5406-18-8
3-(p-methoxyphenyl)-1-propanol

: 1381772-20-8
(E)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

: 1381772-24-2
(Z)-1-(1-(4-methoxyphenyl)-5-(4-nitrophenyl)pentan-3-ylidene)-2-p-tolylhydrazine

Guidance literature:: Multi-step reaction with 4 steps

1: oxalyl dichloride; triethylamine / dichloromethane; dimethyl sulfoxide / 0.5 h / -78 °C / Inert atmosphere

2: diethyl ether / 1 h / 0 °C / Inert atmosphere

3: palladium diacetate; triethylamine / acetonitrile / 17 h / Reflux; Inert atmosphere

4: dichloromethane / 17 h / Molecular sieve; Inert atmosphere; Reflux

With oxalyl dichloride; palladium diacetate; triethylamine; In diethyl ether; dichloromethane; dimethyl sulfoxide; acetonitrile; 1: Swern oxidation / 3: Heck reaction;
DOI:10.1021/ja303054c