ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate

Base Information

Chemical Name:ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate
CAS No.:1138529-99-3
Molecular Formula:C₁₇H₃₂O₃Si
Molecular Weight:312.525
Hs Code.:

Synonyms:ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate

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Chemical Property of ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate

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Technology Process of ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate

There total 1 articles about ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1138530-46-7
ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-oxocyclohexanecarboxylate

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1138529-99-3
ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate

Guidance literature:: Methyltriphenylphosphonium bromide; With n-butyllithium; In diethyl ether; hexane; at 20 ℃; for 0.5h; Inert atmosphere;

ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-oxocyclohexanecarboxylate; In diethyl ether; hexane; at 20 ℃; Inert atmosphere; Reflux;
DOI:10.1021/jo900088x

Reference yield:

: 3278-34-0
ethyl 2-(ethoxythiocarbonylthio)acetate

: 1138529-99-3
ethyl 1-((tert-butyldimethylsilyloxy)methyl)-2-methylenecyclohexanecarboxylate

: ethyl 2-azido-1-[(tert-butyldimethylsilyloxy)methyl]-2-(3-ethoxy-3-oxopropyl)cyclohexanecarboxylate

: ethyl 2-azido-1-[(tert-butyldimethylsilyloxy)methyl]-2-(3-ethoxy-3-oxopropyl)cyclohexanecarboxylate

Guidance literature:: With di-tert-butoxydiazene; bis(tri-n-butyltin); pyridine-3-sulfonyl azide; In benzene; at 70 - 80 ℃; for 1.5h; optical yield given as %de;
DOI:10.1021/jo900088x