{Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}⁽¹⁺⁾*NO₃^(1-)={Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}NO₃

Base Information

• Chemical Name: {Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}⁽¹⁺⁾*NO₃^(1-)={Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}NO₃
• CAS No.: 132673-21-3
• Molecular Formula: C₃₉H₄₈ClIrN₂O₅P₂Tl*NO₃
• Molecular Weight: 1180.83

Synonyms:{Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}⁽¹⁺⁾*NO₃^(1-)={Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}NO₃

Chemical Property of {Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}⁽¹⁺⁾*NO₃^(1-)={Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}NO₃

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Technology Process of {Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}⁽¹⁺⁾*NO₃^(1-)={Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}NO₃

There total 1 articles about {Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}⁽¹⁺⁾*NO₃^(1-)={Tl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl}NO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

thallium(I) nitrate + chlorodicarbonyl(p-toluidine)iridium (14243-22-2,59952-74-8) + crown-P2 (128496-90-2) → {Tl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl}(1+)*NO3(1-)={Tl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl}NO3 (132673-21-3)

Guidance literature:

In toluene; slow addn. of the Ir compd. in toluene to the ligand in toluene over 1 h, evapn. (vac.), dissolving in CH2Cl2, addn. of solid TlNO3 and stirring for 1 h; filtn. and addn. of Et2O;

DOI:10.1021/ja00008a030

Reference yield: 93.0%

{Tl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl}(1+)*NO3(1-)={Tl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl}NO3 (132673-21-3) → {ITl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)ClI}(1+)*NO3(1-)={ITl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)ClI}NO3

Guidance literature:

With I₂; In dichloromethane; addn. of I2 in CH2Cl2 to a stirred soln. of the Ir-Tl compd. in CH2Cl2 and stirring for 20 min; concn., addn. of Et2O, filtn., washing with Et2O and drying (vac.); elem. anal.;

DOI:10.1021/ja00008a030

Reference yield: 82.0%

{Tl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl}(1+)*NO3(1-)={Tl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl}NO3 (132673-21-3) + (Dichloroiodo)benzene (932-72-9) → {ClTl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl2}(1+)*NO3(1-)={ClTl(N(C6H12O2)2N(CH2P(C6H5)2)2)Ir(CO)Cl2}NO3 (132698-26-1)

Guidance literature:

In dichloromethane; addn. of solid PhICl2 in one portion to the Ir-Tl compd. in CH2Cl2 at -50°C, stirring for 20 min and warming to room temp.; addn. of Et2O, cooling to -20°C, standing overnight, filtn., washing with Et2O and drying (vac.); elem. anal.;

DOI:10.1021/ja00008a030

upstream raw materials:

chlorodicarbonyl(p-toluidine)iridium

crown-P₂

Downstream raw materials:

{ClTl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl₂}⁽¹⁺⁾*NO₃^(1-)={ClTl(N(C₆H₁₂O₂)2N(CH₂P(C₆H₅)2)2)Ir(CO)Cl₂}NO₃

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