1-Formyl-o-carborane

Base Information

Chemical Name:1-Formyl-o-carborane
CAS No.:20394-07-4
Molecular Formula:C3H12 B10 O
Molecular Weight:172.238
Hs Code.:

Synonyms:1-Formyl-1,2-dicarbadodecaborane(12);1-Formyl-o-carborane; C-Formyl-o-carborane

Suppliers and Price of 1-Formyl-o-carborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of 1-Formyl-o-carborane

Chemical Property:

Melting Point:206-207 °C
PSA：17.07000
LogP:-6.50730

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-Formyl-o-carborane

There total 2 articles about 1-Formyl-o-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 19610-34-5
(1'-hydroxymethyl)-1,2-dicarba-closo-dodecaborane

: 16872-09-6
1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 20394-07-4
1-formyl-o-carborane

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; oxalyl chloride soln. was cooled to -78 °C; addn. of DMSO; stirring; addn. of (hydroxymethyl)-o-carborane; stirring for 15 min; addn. of Et3N and was allowed to warm to room temp.; addn. of water; extn. three times with CH2Cl2;; the combined org. phase was washed with H2O, dried over MgSO4; the filtered soln. was concd; extn. with pentane; sublimation of the solid followed by chromy. on silica gel by eluting with ether/hexane gave the products;;

Reference yield:

: C₁₆H₂₅B₁₀NO₄

: 20394-07-4
1-formyl-o-carborane

: 7588-36-5
methyl (5-methoxy-2-methyl-1H-indol-3-yl)acetate

Guidance literature:: With sodium tetrahydroborate; In tetrahydrofuran; at 20 ℃; Inert atmosphere;
DOI:10.1039/c4dt03218g

Reference yield: 93.0%

: 20394-07-4
1-formyl-o-carborane

: 624-31-7
4-tolyl iodide

: C₃₁H₃₆B₁₀O

Guidance literature:: 1-formyl-o-carborane; With glycine; at 40 ℃; for 1h; Inert atmosphere; Sealed tube;

4-tolyl iodide; With silver orthophosphate; palladium diacetate; sodium hydrogencarbonate; at 80 ℃; for 24h; Inert atmosphere; Sealed tube;
DOI:10.1021/acscatal.1c04473