(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde

Base Information

Chemical Name:(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde
CAS No.:159351-19-6
Molecular Formula:C₁₈H₃₀O₂SSi
Molecular Weight:338.587
Hs Code.:

Synonyms:(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde

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Chemical Property of (R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde

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Technology Process of (R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde

There total 11 articles about (R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 159351-18-5
(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butan-1-ol

: 159351-19-6
(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde

Guidance literature:: With N-methyl-2-indolinone; tetrapropylammonium perruthennate; In dichloromethane;
DOI:10.1055/s-1994-25589

Reference yield: 65.0%

: 218434-97-0
(R)-2-(tert-Butyl-dimethyl-silanyloxy)-N-methoxy-3,3,N-trimethyl-4-phenylsulfanyl-butyramide

: 159351-19-6
(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde

Guidance literature:: With diisobutylaluminum hydride; In hexane; dichloromethane; at -78 ℃; for 2h;
DOI:10.1016/S0040-4020(98)00889-8

Reference yield:

: 133094-78-7
3-(tert-butyldimethylsilanyloxy)-4,4-dimethyldihydro-2(3H)-furan-2-one

: 159351-19-6
(R)-2-(tert-Butyl-dimethyl-silanyloxy)-3,3-dimethyl-4-phenylsulfanyl-butyraldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / Me₃Al / hexane; benzene / 1 h / Ambient temperature

2: CBr₄, PPh₃ / acetonitrile / 2 h / Ambient temperature

3: DBU / benzene / 48 h / Heating

4: 65 percent / di-isobutylaluminium hydride / hexane; CH₂Cl₂ / 2 h / -78 °C

With diisobutylaluminum hydride; carbon tetrabromide; trimethylaluminum; 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine; In hexane; dichloromethane; acetonitrile; benzene;
DOI:10.1016/S0040-4020(98)00889-8