methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate

Base Information

Chemical Name:methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate
CAS No.:1196473-99-0
Molecular Formula:C₁₅H₁₅BO₆S
Molecular Weight:334.158
Hs Code.:

Synonyms:methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate

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Technology Process of methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate

There total 4 articles about methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 66-27-3
Methyl methanesulfonate

: 1196474-93-7
4-phenoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde

: 1196473-99-0
methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate

Guidance literature:: Methyl methanesulfonate; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.333333h;

4-phenoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde; In tetrahydrofuran; hexane; at -78 - 20 ℃;

Reference yield:

: 59142-68-6
2-bromo-4-fluorobenzaldehyde

: 1196473-99-0
methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 20 - 100 °C

2.1: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 1.5 h / 80 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 0.33 h / -78 °C

3.2: -78 - 20 °C

With n-butyllithium; potassium acetate; potassium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; 1,4-dioxane; hexane; N,N-dimethyl-formamide;

Reference yield:

: 1196474-92-6
2-bromo-4-phenoxybenzaldehyde

: 1196473-99-0
methyl (1-hydroxy-6-phenoxy-1,3-dihydrobenzo[c][1,2]oxaborol-3-yl)methanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 1.5 h / 80 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.33 h / -78 °C

2.2: -78 - 20 °C

With n-butyllithium; potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; 1,4-dioxane; hexane;