phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

Base Information

Chemical Name:phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside
CAS No.:1083236-85-4
Molecular Formula:C₃₈H₄₂O₇S
Molecular Weight:642.813
Hs Code.:

Synonyms:phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

Suppliers and Price of phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

There total 1 articles about phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1083236-84-3
phenyl 2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

: 24424-99-5
di-tert-butyl dicarbonate

: 1083236-85-4
phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃;
DOI:10.1021/jo801630m

Reference yield: 70.0%

: 1083236-85-4
phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

: 1083236-86-5
2,4,6-tri-O-benzyl-1,3-O-carbonyl-α-D-allose

Guidance literature:: phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside; With 1-(phenylsulfonyl)piperidine; 2,4,5-tri-tert-butylpyrimidine; In dichloromethane; at -60 ℃; for 0.166667h; Molecular sieve; Inert atmosphere;

With trifluoromethylsulfonic anhydride; In dichloromethane; at -60 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jo801630m

Reference yield: 56.0%

: 1083236-85-4
phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside

: 108-93-0
cyclohexanol

: 1083236-86-5
2,4,6-tri-O-benzyl-1,3-O-carbonyl-α-D-allose

: 1083236-89-8
cyclohexyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-β-D-allopyranoside

: 1083236-87-6
cyclohexyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-α-D-allopyranoside

Guidance literature:: phenyl 3-O-tert-butoxycarbonyl-2,4,6-tri-O-benzyl-1-thio-β-D-allopyranoside; With 1-(phenylsulfonyl)piperidine; 2,4,5-tri-tert-butylpyrimidine; In dichloromethane; at -60 ℃; for 0.166667h; Molecular sieve; Inert atmosphere;

With trifluoromethylsulfonic anhydride; In dichloromethane; Inert atmosphere; Cooling;

cyclohexanol; In dichloromethane; at -60 ℃; for 2h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/jo801630m