hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

Base Information

Chemical Name:hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate
CAS No.:841234-04-6
Molecular Formula:C₈₄H₁₀₉N₁₁O₁₅
Molecular Weight:1512.85
Hs Code.:

hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

Synonyms:hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

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Chemical Property of hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

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Technology Process of hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

There total 1 articles about hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 841233-97-4
4'-(3,5-diiodo-4-methoxyphenyl)[2,2':6',2'']terpyridine

: [5-tert-butoxycarbonylamino-3-(2-tert-butoxycarbonylamino-ethyl)-3-(4-ethynyl-benzoylamino)-pentyl]-carbamic acid tert-butyl ester

: 841234-04-6
hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

Guidance literature:: With copper(l) iodide; tetrabutylammomium bromide; diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; at 20 ℃; for 16h;
DOI:10.1002/hlca.200490262

Reference yield: 66.0%

: 17084-13-8
potassium hexafluorophosphate

: 841234-12-6
trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III)

: 841234-04-6
hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

: [Ru(C₁₄₈H₁₈₄N₁₆O₁₈)]⁽²⁺⁾*2PF₆^(1-)=[Ru(C₁₄₈H₁₈₄N₁₆O₁₈)](PF₆)2

Guidance literature:: With N-ethylmorpholine; In ethanol; Ru complex and ligand (1 equiv.) were subsequently suspnd. in EtOH and N-ethylmorpholine; mixt. was refluxed for 6 h under Ar; concd.; added dropwise to satd. aq. soln. of KPF6; filtered; washed (EtOH, dil. aq. KPF6); gel-permeation chromd. (Bio-Beads S-X1; CH2Cl2);
DOI:10.1002/hlca.200490262

Reference yield: 52.0%

: 17084-13-8
potassium hexafluorophosphate

: 841234-18-2
trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)

: 841234-04-6
hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

: Ru⁽²⁺⁾*C₁₃₂H₂₀₅N₁₁O₉*(((CH₃)3COCONHC₂H₄)3CNHC(O)C₆H₄CC)2(CH₃O)C₆H₂C₅H₂N(C₅H₄N)2*2PF₆^(1-)=[Ru(C₂₁₆H₃₁₄N₂₂O₂₄)](PF₆)2

Guidance literature:: With N-ethylmorpholine; In 2-methoxy-ethanol; Ru complex and ligand were suspnd. in 2-methoxyethanol and N-ethylmorpholine; mixt. was refluxed for 6 h under Ar; cooled; CH2Cl2 and satd. aq. soln. of KPF6 were added; septd.; aq. phase extd. (CH2Cl2); combined org. phase dried (MgSO4); evapd.; redissolved in CH2Cl2; stirred with satd. aq. soln. of KPF6 for 1 h; septd.; repeated twice; evapd.; dried (P2O5); gel-permeation chromd. (Bio-Beads S-X1; CH2Cl2);
DOI:10.1002/hlca.200490262