trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)

Base Information

Chemical Name:trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)
CAS No.:841234-18-2
Molecular Formula:C₁₃₂H₂₀₅Cl₃N₁₁O₉Ru
Molecular Weight:2297.58
Hs Code.:

trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)

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Chemical Property of trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)

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Technology Process of trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)

There total 1 articles about trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 20759-14-2,14898-67-0
ruthenium(III) chloride hydrate

: N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide

: 841234-18-2
trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)

Guidance literature:: In 2-methoxy-ethanol; suspn. of ligand and RuCl3*H2O in 2-methoxyethanol was refluxed for 6 h under Ar; cooled; MeOH added; filtered; washed (H2O, MeOH); dried;
DOI:10.1002/hlca.200490262

Reference yield: 52.0%

: 17084-13-8
potassium hexafluorophosphate

: 841234-18-2
trichloro-(N,N',N'',N''',N'''',N'''''-hexadodecyl-3,3',3'',3''',3'''',3'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)])hexapropaneamide)ruthenium(III)

: 841234-04-6
hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

: Ru⁽²⁺⁾*C₁₃₂H₂₀₅N₁₁O₉*(((CH₃)3COCONHC₂H₄)3CNHC(O)C₆H₄CC)2(CH₃O)C₆H₂C₅H₂N(C₅H₄N)2*2PF₆^(1-)=[Ru(C₂₁₆H₃₁₄N₂₂O₂₄)](PF₆)2

Guidance literature:: With N-ethylmorpholine; In 2-methoxy-ethanol; Ru complex and ligand were suspnd. in 2-methoxyethanol and N-ethylmorpholine; mixt. was refluxed for 6 h under Ar; cooled; CH2Cl2 and satd. aq. soln. of KPF6 were added; septd.; aq. phase extd. (CH2Cl2); combined org. phase dried (MgSO4); evapd.; redissolved in CH2Cl2; stirred with satd. aq. soln. of KPF6 for 1 h; septd.; repeated twice; evapd.; dried (P2O5); gel-permeation chromd. (Bio-Beads S-X1; CH2Cl2);
DOI:10.1002/hlca.200490262