trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III)

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Chemical Name:trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III)
CAS No.:841234-12-6
Molecular Formula:C₆₄H₇₅Cl₃N₅O₃Ru
Molecular Weight:1169.76
Hs Code.:

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Chemical Property of trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III)

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Technology Process of trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III)

There total 1 articles about trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 20759-14-2,14898-67-0
ruthenium(III) chloride hydrate

: 841234-02-4
N,N'-didodecyl-4,4'-{[2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl)}dibenzamide

: 841234-12-6
trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III)

Guidance literature:: In ethanol; suspn. of RuCl3*H2O and ligand in ethanol was refluxed for 6 h under Ar; cooled; filtered; washed (H2O, EtOH); dried;
DOI:10.1002/hlca.200490262

Reference yield: 66.0%

: 17084-13-8
potassium hexafluorophosphate

: 841234-12-6
trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III)

: 841234-04-6
hexa(tert-butyl) N,N',N'',N''',N'''',N'''''-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis{[(ethyne-2,1-diyl)(benzene-4,1-diyl)(oxomethanediyl)(iminomethanetetrayl)]tris(ethane-2,1-diyl)})hexacarbonate

: [Ru(C₁₄₈H₁₈₄N₁₆O₁₈)]⁽²⁺⁾*2PF₆^(1-)=[Ru(C₁₄₈H₁₈₄N₁₆O₁₈)](PF₆)2

Guidance literature:: With N-ethylmorpholine; In ethanol; Ru complex and ligand (1 equiv.) were subsequently suspnd. in EtOH and N-ethylmorpholine; mixt. was refluxed for 6 h under Ar; concd.; added dropwise to satd. aq. soln. of KPF6; filtered; washed (EtOH, dil. aq. KPF6); gel-permeation chromd. (Bio-Beads S-X1; CH2Cl2);
DOI:10.1002/hlca.200490262