Dibutyl 2-butenedioate homopolymer

Base Information

• Chemical Name: Dibutyl 2-butenedioate homopolymer
• CAS No.: 29014-71-9
• Molecular Formula: C₁₂H₂₀O₄
• Molecular Weight: 228.288
• Mol file: 29014-71-9.mol

Synonyms:2-Butenedioicacid (2E)-, dibutyl ester, homopolymer (9CI); 2-Butenedioic acid (E)-, dibutylester, homopolymer; Fumaric acid, dibutyl ester, polymers (8CI); Dibutylfumarate homopolymer; Dibutyl fumarate polymer; Poly(di-n-butyl fumarate);Poly(dibutyl fumarate)

Chemical Property of Dibutyl 2-butenedioate homopolymer

Chemical Property:

Purity/Quality:

99.0%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dibutyl 2-butenedioate homopolymer

There total 45 articles about Dibutyl 2-butenedioate homopolymer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

maleic anhydride (108-31-6) + butan-1-ol (71-36-3) → Dibutyl maleate (105-76-0,29014-71-9)

Guidance literature:

With diacidic ionic liquid supported on magnetic-silica nanoparticles; In neat (no solvent); at 118 ℃; for 3h; Dean-Stark;

DOI:10.1007/s13738-018-1450-8

Reference yield: 98.0%

maleic anhydride (108-31-6) + butan-1-ol (71-36-3) → dibutyl fumarate (105-75-9,29014-71-9)

Guidance literature:

With sulfuric acid; acetonitrile; at 80 - 85 ℃; for 16 - 18h;

DOI:10.1080/00397911.2013.837485

Reference yield: 94.0%

(2E)-but-2-enedioic acid (110-17-8,26099-09-2) + butan-1-ol (71-36-3) → dibutyl fumarate (105-75-9,29014-71-9)

Guidance literature:

With sulfuric acid; at 120 ℃; for 16h;

DOI:10.1021/ja504727u

upstream raw materials:

maleic acid

butan-1-ol

carbon monoxide

acetylene

Downstream raw materials:

butoxy-succinic acid dibutyl ester

di-n-butyl 2-sulfosuccinate sodium salt

2-Morpholino-bernsteinsaeure-dibutylester

C₃₂H₃₁IO₄

Refernces

• 1、 Abuhafez, Naba,Bruneau, Christian,Gramage-Doria, Rafael,Kamaraj, Raghu,Ruffin, Hervé. "Ruthenium-catalysed oxidative coupling of vinyl derivatives and application in tandem hydrogenation". . p. 5772 - 5776. Retrieved 2021/09/10.
• 2、 -. "Method for preparing olefin by catalyzing dehydration and deoxidation of polyhydroxy compound with organic molybdenum". Paragraph 0109; 0111-0112; 0129; 0131-0132. . Retrieved 2020/07/02.