(1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde

Base Information

Chemical Name:(1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde
CAS No.:868048-07-1
Molecular Formula:C₁₂H₂₂O₄
Molecular Weight:230.304
Hs Code.:

Synonyms:(1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde

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Chemical Property of (1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde

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Technology Process of (1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde

There total 4 articles about (1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 868048-06-0
(1S,3R,4S)-3-hydroxymethyl-4-methoxymethoxy-2,2,4-trimethyl-cyclohexanol

: 868048-07-1
(1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde

Guidance literature:: With sodium hypochlorite; sodium hydrogencarbonate; potassium bromide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrabutyl-ammonium chloride; In dichloromethane; water; at 0 ℃;
DOI:10.1016/j.tet.2005.07.087

Reference yield:

: 868048-04-8
(1S,2S,5S)-2-hydroxy-2,8,8-trimethyl-6-oxabicyclo[3.2.1]octan-7-one

: 868048-07-1
(1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / diisopropylethylamine / CH₂Cl₂ / 48 h / 20 °C

2: 98 percent / lithium aluminum hydride / diethyl ether / 3 h / 20 °C

3: 78 percent / sodium hypochlorite; potassium bromide; sodium bicarbonate / 2,2,6,6-tetramethylpiperidinyl-1-oxy; tetrabutylammonium chloride / CH₂Cl₂; H₂O / 0 °C

With sodium hypochlorite; lithium aluminium tetrahydride; sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine; potassium bromide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrabutyl-ammonium chloride; In diethyl ether; dichloromethane; water;
DOI:10.1016/j.tet.2005.07.087

Reference yield:

: 868048-05-9
(1S,2S,5S)-2-methoxymethoxy-2,8,8-trimethyl-6-oxabicyclo[3.2.1]octan-7-one

: 868048-07-1
(1S,3S,6S)-3-hydroxy-6-methoxymethoxy-2,2,6-trimethyl-cyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / lithium aluminum hydride / diethyl ether / 3 h / 20 °C

2: 78 percent / sodium hypochlorite; potassium bromide; sodium bicarbonate / 2,2,6,6-tetramethylpiperidinyl-1-oxy; tetrabutylammonium chloride / CH₂Cl₂; H₂O / 0 °C

With sodium hypochlorite; lithium aluminium tetrahydride; sodium hydrogencarbonate; potassium bromide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrabutyl-ammonium chloride; In diethyl ether; dichloromethane; water;
DOI:10.1016/j.tet.2005.07.087