Technology Process of 1,3,5,7-tetramethyl-2,6-bis(2-methoxycarbonylethyl)-8-[4-(N,N-diethylamino)phenyl]-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene
There total 2 articles about 1,3,5,7-tetramethyl-2,6-bis(2-methoxycarbonylethyl)-8-[4-(N,N-diethylamino)phenyl]-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
4-Diethylaminobenzaldehyde; methyl 2,4-dimethyl-3-pyrrolepropionate;
With
trifluoroacetic acid;
In
dichloromethane;
at 20 ℃;
Inert atmosphere;
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane;
at 20 ℃;
for 1h;
Inert atmosphere;
With
boron trifluoride diethyl etherate; triethylamine;
In
1,2-dichloro-ethane;
for 0.666667h;
Reflux;
Inert atmosphere;
DOI:10.1039/c1cc12947c
- Guidance literature:
-
With
boron trifluoride diethyl etherate; N-ethyl-N,N-diisopropylamine;
In
toluene;
at 20 ℃;
for 0.166667h;
- Guidance literature:
-
1,3,5,7-tetramethyl-2,6-bis(2-methoxycarbonylethyl)-8-[4-(N,N-diethylamino)phenyl]-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene;
With
sodium hydroxide; water;
In
methanol; dichloromethane; acetone;
at 20 ℃;
for 4h;
With
hydrogenchloride;
In
methanol; dichloromethane; water;
UV-irradiation;
