2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

Base Information

Chemical Name:2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene
CAS No.:877995-21-6
Molecular Formula:C₄₀H₇₆Si₆Sn
Molecular Weight:844.266
Hs Code.:

Synonyms:2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

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Chemical Property of 2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

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Technology Process of 2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

There total 3 articles about 2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 877995-24-9
(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)tribromostannane

: 211508-96-2
3-tert-butyl-1H-isotellurochromene

: 877995-21-6
2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

Guidance literature:: With n-BuLi; LiAlH₄; In tetrahydrofuran; react. isotellurochromene with BuLi in THF at -78°C, Sn-compound was added in THF at -78°C, excess LiAlH4 was added in THF at 0°C;
DOI:10.1021/ja057531d

Reference yield: 37.0%

: 135139-65-0
2,4,6-tris[bis(trimethylsilyl)methyl]phenyl-trichloro stannane

: 211508-96-2
3-tert-butyl-1H-isotellurochromene

: 877995-21-6
2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

Guidance literature:: With n-BuLi; LiAlH₄; In tetrahydrofuran; react. isotellurochromene with BuLi in THF at -78°C, Sn-compound was added in THF at -78°C, excess LiAlH4 was added in THF at 0°C;
DOI:10.1021/ja057531d

Reference yield:

: 16853-85-3
lithium aluminium tetrahydride

: 877995-22-7
2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-bromo-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

: 1068655-40-2
2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-chloro-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

: 877995-21-6
2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-3-tert-butyl-1,2-dihydro-2-stannanaphthalene

Guidance literature:: In tetrahydrofuran; (Ar); LiAlH4 was added to mixt. of Sn compd. in THF at 0°C; stirred at 0°C for 1 h; EtOAc added at 0°C; solvent removed; hexane added; filtered through Celite; solvent removed; wet column chromd. (hexane); elem. anal.;
DOI:10.1039/b718193k