(k⁴-N(CH₂CH₂PPh₂)₃)RuCl₂

Base Information

• Chemical Name: (k⁴-N(CH₂CH₂PPh₂)₃)RuCl₂
• CAS No.: 85436-56-2
• Molecular Formula: C₄₂H₄₂Cl₂NP₃Ru
• Molecular Weight: 825.699
• Mol file: 85436-56-2.mol

Synonyms:(k⁴-N(CH₂CH₂PPh₂)₃)RuCl₂

Chemical Property of (k⁴-N(CH₂CH₂PPh₂)₃)RuCl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (k⁴-N(CH₂CH₂PPh₂)₃)RuCl₂

There total 2 articles about (k⁴-N(CH₂CH₂PPh₂)₃)RuCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + tris(2-(diphenylphosphino)ethyl)amine (15114-55-3) → (k4-N(CH2CH2PPh2)3)RuCl2 (85436-56-2)

Guidance literature:

In toluene; under inert atmosphere; dropwise addn. of dissolved amine to Ru-complex soln. at room temp.; refluxing for 5 h; evapd. under reduced pressure; elem. anal.; NMR;

DOI:10.1016/0022-328X(91)83145-T

Reference yield: 50.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + tris(2-(diphenylphosphino)ethyl)amine (15114-55-3) → dichlorotris(2-(diphenylphosphino)ethyl)amineruthenium(II) (85436-56-2)

Guidance literature:

In benzene; equimolar amts. of RuCl and ligand TPEA refluxed (6 h); cooled soln. filtered and concd. to a small vol.; addn. of ether; ppt. washed (ether); elem. anal.;

Reference yield: 78.0%

(k4-N(CH2CH2PPh2)3)RuCl2 (85436-56-2) → (N(CH2CH2P(C6H5)2)3)RuH(C6H5)

Guidance literature:

With NaHg; In benzene; under inert atmosphere; stirred for 60 h at room temp.; filtered; evapd. to dryness; dissolved (C6H6); filtered; solvent was removed; elem. anal.; IR; NMR;

DOI:10.1016/0022-328X(91)83145-T

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

tris(2-(diphenylphosphino)ethyl)amine

Downstream raw materials:

[Ru(κ4-(tris-(2-(diphenylphosphino)ethyl)amine))Cl(H)]

[Ru(κ4-(tris-(2-(diphenylphosphino)ethyl)amine))(η2-H2)(H)]+

[Ru(κ4-(tris-(2-(diphenylphosphino)ethyl)amine))Cl(η2-H2)]+