O-NITROPHENYL LAURATE

Base Information

• Chemical Name: O-NITROPHENYL LAURATE
• CAS No.: 2639-52-3
• Molecular Formula: C18H27 N O4
• Molecular Weight: 321.41128
• Mol file: 2639-52-3.mol

Synonyms:Lauricacid, o-nitrophenyl ester (7CI); 2-Nitrophenyl laurate

Chemical Property of O-NITROPHENYL LAURATE

Chemical Property:

• PSA: 72.12000
• LogP: 5.94430
• Storage Temp.: −20°C

Purity/Quality:

97% ^*data from raw suppliers

2-Nitrophenyl laurate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of O-NITROPHENYL LAURATE

There total 2 articles about O-NITROPHENYL LAURATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.8%

n-dodecanoyl chloride (112-16-3) + 2-hydroxynitrobenzene (88-75-5,78813-12-4) → 2-nitrophenyl dodecanoate (2639-52-3)

Guidance literature:

In diethyl ether; Heating;

DOI:10.1007/s00044-010-9383-5

Reference yield:

lauric acid (143-07-7) → 2-nitrophenyl dodecanoate (2639-52-3)

Guidance literature:

Multi-step reaction with 2 steps

1: thionyl chloride

2: diethyl ether / Heating

With thionyl chloride; In diethyl ether;

DOI:10.1007/s00044-010-9383-5

Reference yield:

2-nitrophenyl dodecanoate (2639-52-3) → 2-Nitrophenolate ion (16554-53-3) + laurate anion (115-05-9)

Guidance literature:

With hydroxide; CTAB-micelle; In acetonitrile; at 25 ℃; Rate constant; pH- and CTAB-conc. dependence;

DOI:10.1021/jo00294a009

upstream raw materials:

n-dodecanoyl chloride

2-hydroxynitrobenzene

lauric acid

Downstream raw materials:

2-Nitrophenolate ion

laurate anion

Refernces

• 1、 Al-Awadi, Nouria,Williams, Andrew. "Effective Charge Development in Ester Hydrolysis Catalyzed by Cationic Micelles". . p. 2001 - 2004. Retrieved 2007/10/02.