but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester

Base Information

Chemical Name:but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester
CAS No.:942063-15-2
Molecular Formula:C₂₄H₄₀O₃Si
Molecular Weight:404.665
Hs Code.:

Synonyms:but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester

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Chemical Property of but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester

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Technology Process of but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester

There total 4 articles about but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 942063-14-1
7-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]heptan-2-ol

: 623-68-7
trans-crotonic anhydride

: 942063-15-2
but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 ℃; for 4h;
DOI:10.1021/ol0704901

Reference yield:

: C₁₅H₂₉OB

: 942063-15-2
but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 2.73 g / K₃PO₄ / PdCl₂(dppf)*CH₂Cl₂ / H₂O; tetrahydrofuran / 16 h / 20 °C

2: 84 percent / triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 4 h / 0 °C

With dmap; potassium phosphate; triethylamine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In tetrahydrofuran; dichloromethane; water; 1: Suzuki coupling;
DOI:10.1021/ol0704901

Reference yield:

: 24395-10-6,88932-32-5,88980-13-6,144178-30-3
(R)-hept-6-en-2-ol

: 942063-15-2
but-2-enoic acid 4-[2-((tert-butyldimethylsilanyloxy)methyl)phenyl]-1-methylhexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: tetrahydrofuran / 0 - 20 °C

2: 2.73 g / K₃PO₄ / PdCl₂(dppf)*CH₂Cl₂ / H₂O; tetrahydrofuran / 16 h / 20 °C

3: 84 percent / triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 4 h / 0 °C

With dmap; potassium phosphate; triethylamine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In tetrahydrofuran; dichloromethane; water; 2: Suzuki coupling;
DOI:10.1021/ol0704901