[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]PF₆

Base Information

• Chemical Name: [(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]PF₆
• CAS No.: 405316-11-2
• Molecular Formula: C₂₄H₃₉ClIrN₂*F₆P
• Molecular Weight: 728.224

Synonyms:[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]PF₆

Chemical Property of [(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]PF₆

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Technology Process of [(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]PF₆

There total 1 articles about [(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5ClIr]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + N,N'-di-cyclohexyl-1,4-diazabuta-1,3-diene + tert-butylammonium hexafluorophosphate(V) (3109-63-5) → [(C6H11NCHCHNC6H11)C5(CH3)5ClIr](1+)*PF6(1-)=[(C6H11NCHCHNC6H11)C5(CH3)5ClIr]PF6 (405316-11-2)

Guidance literature:

In methanol; addn. of diene deriv. to a suspn. of Ir compd. in MeOH (ultrasonic bath); mixt. stirred for 3 h at room temp.; concn. of soln.; addn. of (C4H9)4PF6 soln. in methanol; ppt. collected, washed with MeOH and Et2O, dried in vac.; elem. anal.;

DOI:10.1021/om010529k

Reference yield: 65.0%

[(C6H11NCHCHNC6H11)C5(CH3)5ClIr](1+)*PF6(1-)=[(C6H11NCHCHNC6H11)C5(CH3)5ClIr]PF6 (405316-11-2) → (C6H11NCHCHNC6H11)C5(CH3)5Ir (405316-14-5)

Guidance literature:

With (C₄H₉)NBH₄; In acetone; react. of soln. of Ir complex in acetone at -15°C with (C4H9)N4BH4; soln. concd., degassed water added, ppt. collected, washed with water, dried in vac.; elem. anal.;

DOI:10.1021/om010529k

Reference yield: 55.0%

[(C6H11NCHCHNC6H11)C5(CH3)5ClIr](1+)*PF6(1-)=[(C6H11NCHCHNC6H11)C5(CH3)5ClIr]PF6 (405316-11-2) + sodium cyanoborohydride (25895-60-7) → [(C6H11NHCH2CHNC6H11)C5(CH3)5HIr](1+)*PF6(1-)=[(C6H11NHCH2CHNC6H11)C5(CH3)5HIr]PF6 (405316-07-6)

Guidance literature:

In ethanol; water; a soln. of Ir complex in ethanol:water (4:1) treated with NaBH3(CN), left for 4 h; slow concn. of soln. until pptn., ppt. collected, washed with degassed water, dried in vac.; elem. anal.;

DOI:10.1021/om010529k

upstream raw materials:

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

tert-butylammonium hexafluorophosphate(V)

Downstream raw materials:

(C₆H₁₁NCHCHNC₆H₁₁)C₅(CH₃)5Ir

(C₆H₁₁NHCH₂CH₂NHC₆H₁₁)C₅(CH₃)5HIr⁽¹⁺⁾*(BH₃CN)^(1-) = (C₆H₁₁NHCH₂CH₂NHC₆H₁₁)C₅(CH₃)5HIr(BH₃CN)

[(C₆H₁₁NHCH₂CHNC₆H₁₁)C₅(CH₃)5HIr]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₁₁NHCH₂CHNC₆H₁₁)C₅(CH₃)5HIr]PF₆

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