[(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6

Base Information

• Chemical Name: [(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6
• CAS No.: 433217-83-5
• Molecular Formula: C₂₀H₂₇FeNO₄P*F₆P
• Molecular Weight: 577.224
• Mol file: 433217-83-5.mol

Synonyms:[(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6

Chemical Property of [(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6

There total 1 articles about [(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6) (89870-08-6) + P(N(SiMe3)Ph)(OMe)2 (433217-88-0) + water (7732-18-5) → [(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6 (433217-83-5)

Guidance literature:

In dichloromethane; under N2, standard Schlenk techniques; soln. of Fe complex in CH2Cl2 treated with P(OMe)2(NPh(SiMe3)) (molar ratio 1:1) at room temp.; stirred overnight; a few drops of H2O added; stirred for 2 h; column chromd. (silica gel, CH2Cl2, CH2Cl2-acetone); pale yellow band collected; dried under vac.; dissolved in small amt. of THF; pptd. by adding large amt. of ether; ppt. washed with ether; dried under reduced pressure; elem. anal.;

DOI:10.1021/om0110484

Reference yield: 68.0%

[(η5-C5Me5)(CO)2Fe(P(NHPh)(OMe)2)]PF6 (433217-83-5) → (η5-C5Me5)(CO)2Fe(P(NPh)(OMe)2)

Guidance literature:

With NaNH₂; In tetrahydrofuran; under N2, standard Schlenk techniques; excess of NaNH2 added to soln. ofFe complex in THF; stirred at room temp. for 30 min; volatiles removed under reduced pressure; extd. with pentane; solvent removed in vac.; washed with small amt. of hexane; elem. anal.;

DOI:10.1021/om0110484

upstream raw materials:

((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6)

P(N(SiMe₃)Ph)(OMe)2

water