3,3′,5,5′-tetrakis(4-pyridyl)bimesityl

Base Information

• Chemical Name: 3,3′,5,5′-tetrakis(4-pyridyl)bimesityl
• CAS No.: 809274-33-7
• Molecular Formula: C₃₈H₃₄N₄
• Molecular Weight: 546.715
• Mol file: 809274-33-7.mol

Synonyms:3,3′,5,5′-tetrakis(4-pyridyl)bimesityl

Chemical Property of 3,3′,5,5′-tetrakis(4-pyridyl)bimesityl

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of 3,3′,5,5′-tetrakis(4-pyridyl)bimesityl

There total 1 articles about 3,3′,5,5′-tetrakis(4-pyridyl)bimesityl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

3,3',5,5'-tetraiodo-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl (37055-19-9) + 4-pyridineboronic acid pinacol ester (181219-01-2) → 3,3′,5,5′-tetrakis(4-pyridyl)bimesityl (809274-33-7)

Guidance literature:

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,4-dioxane; for 48h; Heating;

DOI:10.1002/anie.200461625

Reference yield: 60.0%

3,3′,5,5′-tetrakis(4-pyridyl)bimesityl (809274-33-7) + zinc perchlorate → Zn(3,3',5,5'-tetrakis(4-pyridyl)bimesityl)1.5(ClO4)2*12H2O

Guidance literature:

In methanol; dichloromethane; soln. of Zn(ClO4)2*6H2O in methanol layered over soln. of 3,3',5,5'-tetrakis(4-pyridyl)bimesityl in CH2Cl2; stored at room temp. for 2 d; crystals sepd.; elem. anal.;

DOI:10.1002/anie.200461625

Reference yield: 55.0%

3,3′,5,5′-tetrakis(4-pyridyl)bimesityl (809274-33-7) + methanol (67-56-1) + manganese(II) chloride tetrahydrate → Mn(3,3',5,5'-tetrakis(4-pyridyl)bimesityl)Cl2(CH3OH)(H2O)8

Guidance literature:

In methanol; dichloromethane; soln. of MnCl2*4H2O in methanol layered over soln. of 3,3',5,5'-tetrakis(4-pyridyl)bimesityl in CH2Cl2; allowed to evaporate slowly over 10 d; crystals sepd.; elem. anal.;

DOI:10.1002/anie.200461625

upstream raw materials:

3,3',5,5'-tetraiodo-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl

4-pyridineboronic acid pinacol ester

Refernces