(1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

Base Information

Chemical Name:(1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol
CAS No.:475197-90-1
Molecular Formula:C₁₀H₁₈O₂
Molecular Weight:170.252
Hs Code.:

Synonyms:(1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

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Technology Process of (1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

There total 17 articles about (1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 475197-89-8
(+)-methyl (1'R,3'S)-3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexylcarboxylate

: 475197-90-1
(1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 ℃; for 2h;
DOI:10.1016/S0957-4166(02)00335-X

Reference yield: 75.0%

: 475197-97-8
(1'R,3'S)-cis-(3'-(imidazoylthiocarbonyl)oxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropyonate

: 475197-90-1
(1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

: 166022-29-3
(S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

Guidance literature:: (1'R,3'S)-cis-(3'-(imidazoylthiocarbonyl)oxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropyonate; With n-butyl tin hydride; 2,2'-azobis(isobutyronitrile); In toluene; for 26h; Heating;

With lithium aluminium tetrahydride; In toluene; at 0 ℃; for 1.5h;
DOI:10.1016/S0957-4166(02)00335-X

Reference yield: 7.0%

: 108-05-4,9003-20-7
vinyl acetate

: 72445-03-5,85121-46-6
(1RS,3SR)-3-(hydroxymethyl)-2,2-dimethyl-4-methylenecyclohexanol

: C₁₂H₂₀O₃

: C₁₂H₂₀O₃

: 1178893-08-7
C₁₂H₂₀O₃

: C₁₂H₂₀O₃

: 1178893-12-3
C₁₄H₂₂O₄

: 475197-90-1
(1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

: 171231-07-5
(1S,5R)-cis-3-hydroxy-2,2-dimethyl-6-methylenecyclohexanemethanol

Guidance literature:: With Pseudomonas cepacia lipase; In tert-butyl methyl ether; at 20 ℃; optical yield given as %ee; enantioselective reaction; Resolution of racemate; Enzymatic reaction;
DOI:10.1016/j.tetasy.2009.05.013