(1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate

Base Information

Chemical Name:(1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate
CAS No.:475197-95-6
Molecular Formula:C₁₅H₂₆O₃
Molecular Weight:254.37
Hs Code.:

Synonyms:(1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate

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Chemical Property of (1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate

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Technology Process of (1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate

There total 1 articles about (1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 475197-90-1
(1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

: 3282-30-2
pivaloyl chloride

: 2,2-Dimethyl-propionic acid (1S,3R)-3-hydroxymethyl-2,2-dimethyl-4-methylene-cyclohexyl ester

: 475197-95-6
(1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate

: 2,2-Dimethyl-propionic acid (1S,3R)-3-(2,2-dimethyl-propionyloxymethyl)-2,2-dimethyl-4-methylene-cyclohexyl ester

Guidance literature:: With pyridine; dmap; In dichloromethane; at 25 ℃; for 18h;
DOI:10.1016/S0957-4166(02)00335-X

Reference yield: 92.0%

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 475197-95-6
(1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate

: 475197-97-8
(1'R,3'S)-cis-(3'-(imidazoylthiocarbonyl)oxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropyonate

Guidance literature:: In toluene; for 14h; Heating;
DOI:10.1016/S0957-4166(02)00335-X

Reference yield:

: 475197-95-6
(1'R,3'S)-(-)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methyl 2,2-dimethylpropionate

: 166022-29-3
(S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 92 percent / toluene / 14 h / Heating

2.1: (n-C₄H₉)SnH; azo-bis(isobutyronitrile) / toluene / 26 h / Heating

2.2: 75 percent / LiAlH₄ / toluene / 1.5 h / 0 °C

With n-butyl tin hydride; 2,2'-azobis(isobutyronitrile); In toluene;
DOI:10.1016/S0957-4166(02)00335-X