cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one

Base Information

Chemical Name:cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one
CAS No.:162599-35-1
Molecular Formula:C₂₆H₂₇NO₈
Molecular Weight:481.502
Hs Code.:

Synonyms:cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one

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Chemical Property of cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one

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Technology Process of cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one

There total 3 articles about cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 101067-78-1,101067-80-5,131968-71-3,146924-91-6,146924-94-9,194234-97-4
(+/-)-(3R,4S)-3-hydroxy-4-phenyl-N-(4-methoxyphenyl)azetidin-2-one

: 2873-29-2
D-glucal triacetate

: 162599-35-1
cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one

: 162458-86-8
cis-1-(p-anisyl)-3'R-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4S-phenyl-azetidin-2-one

Guidance literature:: With iodine; In tetrahydrofuran; at 20 ℃; for 30h; stereospecific reaction;
DOI:10.1016/j.tet.2012.01.078

Reference yield:

: 783-08-4
[4-(benzylideneamino)phenyl]methanol

: 162599-35-1
cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane

2: sodium hydroxide; water / tetrahydrofuran

3: iodine / tetrahydrofuran / 30 h / 20 °C

With water; iodine; triethylamine; sodium hydroxide; In tetrahydrofuran; dichloromethane; 3: |Ferrier Carbohydrate Rearrangement;
DOI:10.1016/j.tet.2012.01.078

Reference yield:

: 131968-76-8,135692-75-0,146924-90-5,146924-95-0
(+/-)-(3R,4S)-3-acetoxy-N-(4-methoxyphenyl)-4-phenylazetidin-2-one

: 162599-35-1
cis-1-(p-anisyl)-3'S-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4R-phenyl-azetidin-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide; water / tetrahydrofuran

2: iodine / tetrahydrofuran / 30 h / 20 °C

With water; iodine; sodium hydroxide; In tetrahydrofuran; 2: |Ferrier Carbohydrate Rearrangement;
DOI:10.1016/j.tet.2012.01.078