4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine

Base Information

• Chemical Name: 4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine
• CAS No.: 1104390-10-4
• Molecular Formula: C₂₆H₂₉Br₂NO
• Molecular Weight: 531.33
• Mol file: 1104390-10-4.mol

Synonyms:4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine

Chemical Property of 4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine

There total 12 articles about 4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

N,N-bis(4-bromophenyl)-4-hydroxyphenylamine (336619-79-5) + 1-bromo-octane (111-83-1) → 4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine (1104390-10-4)

Guidance literature:

N,N-bis(4-bromophenyl)-4-hydroxyphenylamine; for 1h; Inert atmosphere; Reflux; Alkaline conditions;

1-bromo-octane; Inert atmosphere; Reflux; Alkaline conditions;

DOI:10.1039/c5nj02124c

Reference yield: 72.0%

4-(octyloxy)-N,N-diphenylbenzenamine → 4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine (1104390-10-4)

Guidance literature:

With N-Bromosuccinimide; acetic acid; In chloroform; at 0 ℃;

DOI:10.1021/acs.macromol.8b00919

Reference yield:

1-bromo-octane (111-83-1) → 4-bromo-N-(4-bromophenyl)-N-(4-(octyloxy)-phenyl)benzenamine (1104390-10-4)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium hydroxide / dimethyl sulfoxide

2.1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tricyclohexylphosphine / toluene / 5 h / 120 °C / Inert atmosphere

3.1: N-Bromosuccinimide; acetic acid / chloroform / 2 h / 0 °C

3.2: 0.5 h

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; N-Bromosuccinimide; acetic acid; potassium hydroxide; sodium t-butanolate; tricyclohexylphosphine; In chloroform; dimethyl sulfoxide; toluene;

DOI:10.1002/pola.26943

upstream raw materials:

N,N-bis(4-bromophenyl)-4-hydroxyphenylamine

1-bromo-octane

tri(p-bromophenyl)amine

1-bromo-4-octyloxybenzene

Downstream raw materials:

4-(octyloxy)-N,N-bis(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline