Technology Process of C31H50O5Si2
There total 3 articles about C31H50O5Si2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide;
In
acetonitrile;
at 82 ℃;
for 3h;
Inert atmosphere;
DOI:10.1021/ol202728v
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: titanium tetrachloride / toluene / 1.17 h / -78 °C / Inert atmosphere
1.2: 3.5 h / -78 - 5 °C
2.1: 1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide / acetonitrile / 3 h / 82 °C / Inert atmosphere
With
titanium tetrachloride; 1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide;
In
toluene; acetonitrile;
1.1: Diels-Alder reaction / 1.2: Diels-Alder reaction;
DOI:10.1021/ol202728v
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sulfur trioxide pyridine complex / dichloromethane; dimethyl sulfoxide / 1.5 h / 0 °C / Inert atmosphere
2.1: titanium tetrachloride / toluene / 1.17 h / -78 °C / Inert atmosphere
2.2: 3.5 h / -78 - 5 °C
3.1: 1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide / acetonitrile / 3 h / 82 °C / Inert atmosphere
With
sulfur trioxide pyridine complex; titanium tetrachloride; 1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide;
In
dichloromethane; dimethyl sulfoxide; toluene; acetonitrile;
1.1: Parikh-Doering oxidation / 2.1: Diels-Alder reaction / 2.2: Diels-Alder reaction;
DOI:10.1021/ol202728v
