naphthalen-1-yl-phenyl-trimethylsilylamine

Base Information

• Chemical Name: naphthalen-1-yl-phenyl-trimethylsilylamine
• CAS No.: 73039-27-7
• Molecular Formula: C₁₉H₂₁NSi
• Molecular Weight: 291.468
• Mol file: 73039-27-7.mol

Synonyms:naphthalen-1-yl-phenyl-trimethylsilylamine

Chemical Property of naphthalen-1-yl-phenyl-trimethylsilylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of naphthalen-1-yl-phenyl-trimethylsilylamine

There total 1 articles about naphthalen-1-yl-phenyl-trimethylsilylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

chloro-trimethyl-silane (75-77-4) + N-phenyl-1-naphthylamine (90-30-2) → naphthalen-1-yl-phenyl-trimethylsilylamine (73039-27-7)

Guidance literature:

N-phenyl-1-naphthylamine; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; at 20 ℃; for 18h;

DOI:10.1039/b509345g

Reference yield: 99.0%

naphthalen-1-yl-phenyl-trimethylsilylamine (73039-27-7) + para-bromotoluene (106-38-7) → N-(4-methylphenyl)-N-phenylnaphthalen-1-amine (138310-86-8)

Guidance literature:

With cesium fluoride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; XPhos; at 100 ℃; for 0.5h; Inert atmosphere;

DOI:10.1246/cl.131075

Reference yield: 53.0%

naphthalen-1-yl-phenyl-trimethylsilylamine (73039-27-7) + 4-methoxycarbonylphenyl bromide (619-42-1) → 4-(naphthalen-1-yl-phenylamino)benzoic acid methyl ester

Guidance literature:

With tri-tert-butyl phosphine; caesium carbonate; cesium fluoride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; carbon dioxide; In hexane; at 100 ℃; for 48h; under 93086.6 Torr;

DOI:10.1039/b509345g

upstream raw materials:

chloro-trimethyl-silane

N-phenyl-1-naphthylamine

Downstream raw materials:

4,4'-bis[N-(1-naphthyl)-N-phenylamino] biphenyl

N-(4-methylphenyl)-N-phenylnaphthalen-1-amine

Refernces