rel-1,1-Dimethylethyl (alphaR,betaR)-beta-hydroxy-alpha-methylbenzenepropanoate

Base Information

Chemical Name:rel-1,1-Dimethylethyl (alphaR,betaR)-beta-hydroxy-alpha-methylbenzenepropanoate
CAS No.:72658-16-3
Molecular Formula:C₁₄H₂₀O₃
Molecular Weight:236.311
Hs Code.:
DSSTox Substance ID:DTXSID701168195
Nikkaji Number:J968.357G

Synonyms:DTXSID701168195;72658-16-3;rel-1,1-Dimethylethyl (alphaR,betaR)-beta-hydroxy-alpha-methylbenzenepropanoate

Suppliers and Price of rel-1,1-Dimethylethyl (alphaR,betaR)-beta-hydroxy-alpha-methylbenzenepropanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of rel-1,1-Dimethylethyl (alphaR,betaR)-beta-hydroxy-alpha-methylbenzenepropanoate

Chemical Property:

XLogP3:2.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:236.14124450
Heavy Atom Count:17
Complexity:249

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C(C1=CC=CC=C1)O)C(=O)OC(C)(C)C
Isomeric SMILES:C[C@H]([C@H](C1=CC=CC=C1)O)C(=O)OC(C)(C)C

Technology Process of rel-1,1-Dimethylethyl (alphaR,betaR)-beta-hydroxy-alpha-methylbenzenepropanoate

There total 11 articles about rel-1,1-Dimethylethyl (alphaR,betaR)-beta-hydroxy-alpha-methylbenzenepropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1663-39-4,25232-27-3
tert-Butyl acrylate

: 100-52-7
benzaldehyde

: 72658-21-0
tert-butyl 3-hydroxy-2-methyl-3-phenylpropionate

: 72658-16-3
tert-butyl 3-hydroxy-2-methyl-3-phenylpropionate

Guidance literature:: With trichlorosilane; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane; at 20 ℃; for 45h; Yield given. Yields of byproduct given;
DOI:10.1016/S0040-4039(98)01030-2

Reference yield:

: 84784-58-7
(E)-[(1-methoxy)-propenyloxy]-tert-butyldimethylsilane

: 100-52-7
benzaldehyde

: 72658-21-0
tert-butyl 3-hydroxy-2-methyl-3-phenylpropionate

: 72658-16-3
tert-butyl 3-hydroxy-2-methyl-3-phenylpropionate

Guidance literature:: (E)-[(1-methoxy)-propenyloxy]-tert-butyldimethylsilane; benzaldehyde; With rhenium(I) pentacarbonyl bromide; In benzene; at 80 ℃; for 1h; under 760.051 Torr; Inert atmosphere;

With hydrogenchloride; water; optical yield given as %de; Inert atmosphere;
DOI:10.1016/j.tetlet.2009.11.109