1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

Base Information

Chemical Name:1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol
CAS No.:92812-65-2
Molecular Formula:C₂₃H₂₆N₆O₅
Molecular Weight:466.497
Hs Code.:

Synonyms:1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

Suppliers and Price of 1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

There total 9 articles about 1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 92812-64-1
Benzoic acid (S)-2-azido-2-((4R,5S,6S)-5-benzyloxy-2,2-dimethyl-6-trifluoromethanesulfonyloxymethyl-[1,3]dioxan-4-yl)-ethyl ester

: 92812-65-2
1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; for 0.5h; Yield given; Ambient temperature;
DOI:10.1016/0008-6215(84)85278-7

Reference yield:

: 37776-15-1
6-O-Benzoyl-3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose

: 92812-65-2
1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

Guidance literature:: Multi-step reaction with 9 steps

1: pyridine / 1,2-dichloro-ethane / 1 h / 0 °C

2: sodium azide / dimethylformamide / 1 h / 70 °C

3: 93 percent / 1 M aqu. sulfuric acid / dioxane / 5 h / 80 °C

4: 81 percent / sodium borohydride / 1,2-dimethoxy-ethane / 1 h / 0 °C

5: 90 percent / pyridine / 1,2-dichloro-ethane / 17 h / 37 °C

6: 99 percent / pyridinium p-toluenesulfonate / 1,2-dichloro-ethane / 2 h / 60 °C

7: 87 percent / tetrabutylammonium fluoride / various solvent(s) / 1 h / 0 °C

8: pyridine / 1,2-dichloro-ethane / 0.25 h / 0 °C

9: sodium azide / dimethylformamide / 0.5 h / Ambient temperature

With pyridine; sodium tetrahydroborate; sodium azide; sulfuric acid; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; In 1,4-dioxane; 1,2-dimethoxyethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(84)85278-7

Reference yield:

: 92840-96-5
5-azido-6-O-benzoyl-3-O-benzyl-5-deoxy-L-iditol

: 92812-65-2
1,5-diazido-6-O-benzoyl-3-O-benzyl-1,5-dideoxy-2,4-O-isopropylidene-L-iditol

Guidance literature:: Multi-step reaction with 5 steps

1: 90 percent / pyridine / 1,2-dichloro-ethane / 17 h / 37 °C

2: 99 percent / pyridinium p-toluenesulfonate / 1,2-dichloro-ethane / 2 h / 60 °C

3: 87 percent / tetrabutylammonium fluoride / various solvent(s) / 1 h / 0 °C

4: pyridine / 1,2-dichloro-ethane / 0.25 h / 0 °C

5: sodium azide / dimethylformamide / 0.5 h / Ambient temperature

With pyridine; sodium azide; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; In 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(84)85278-7