<1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane

Base Information

Chemical Name:<1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane
CAS No.:145668-40-2
Molecular Formula:C₁₄H₂₈OSi
Molecular Weight:240.461
Hs Code.:

Synonyms:<1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane

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Chemical Property of <1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane

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Technology Process of <1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane

There total 5 articles about <1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1779-49-3
Methyltriphenylphosphonium bromide

: 145668-40-2
<1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) potassium tert-butoxide / 1.) THF, 2.) THF, r.t., 20 min

2: 86 percent / DIBAL-H / CH₂Cl₂ / 0.25 h / -50 deg C to 0 deg C

3: 78 percent / H₂ / Rh(Ph₃P)3Cl / CH₂Cl₂ / 16 h / 3620.04 Torr / Ambient temperature

4: 1.) o-nitrophenyl selenocyanate, Bu₃P, 2.) aq.H₂O₂ / 1.) THF, r.t., 1 h, 2.) r.t., 1 h then 55 deg C, 1 h

With ortho-nitrophenyl selenocyanate; tributylphosphine; potassium tert-butylate; hydrogen; dihydrogen peroxide; diisobutylaluminium hydride; Wilkinson's catalyst; In dichloromethane;
DOI:10.1021/jo00056a013

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 145668-40-2
<1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) potassium tert-butoxide / 1.) THF, 2.) THF, r.t., 20 min

2: 86 percent / DIBAL-H / CH₂Cl₂ / 0.25 h / -50 deg C to 0 deg C

3: 78 percent / H₂ / Rh(Ph₃P)3Cl / CH₂Cl₂ / 16 h / 3620.04 Torr / Ambient temperature

4: 1.) o-nitrophenyl selenocyanate, Bu₃P, 2.) aq.H₂O₂ / 1.) THF, r.t., 1 h, 2.) r.t., 1 h then 55 deg C, 1 h

With ortho-nitrophenyl selenocyanate; tributylphosphine; potassium tert-butylate; hydrogen; dihydrogen peroxide; diisobutylaluminium hydride; Wilkinson's catalyst; In dichloromethane;
DOI:10.1021/jo00056a013

Reference yield:

: 145668-36-6
trans-(1S)-2-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-4-methylenecyclohexanecarboxylic acid methyl ester

: 145668-40-2
<1S-trans>-(1,1-dimethylethyl)dimethyl<(5-methyl-2-methylenecyclohexyl)oxy>silane

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / DIBAL-H / CH₂Cl₂ / 0.25 h / -50 deg C to 0 deg C

2: 78 percent / H₂ / Rh(Ph₃P)3Cl / CH₂Cl₂ / 16 h / 3620.04 Torr / Ambient temperature

3: 1.) o-nitrophenyl selenocyanate, Bu₃P, 2.) aq.H₂O₂ / 1.) THF, r.t., 1 h, 2.) r.t., 1 h then 55 deg C, 1 h

With ortho-nitrophenyl selenocyanate; tributylphosphine; hydrogen; dihydrogen peroxide; diisobutylaluminium hydride; Wilkinson's catalyst; In dichloromethane;
DOI:10.1021/jo00056a013