TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE

Base Information

• Chemical Name: TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE
• CAS No.: 93556-88-8
• Molecular Formula: C8H12AgBF4N4
• Molecular Weight: 358.883
• Mol file: 93556-88-8.mol

Synonyms:TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE;tetrakis(acetonitrile)silver(I) tetra-fluoroborat

Chemical Property of TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE

Chemical Property:

• Melting Point: 72-75 °C(lit.)
• PSA: 95.16000
• LogP: 3.41952

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetrakis(acetonitrile)silver(I) tetrafluoroborate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Reactant for synthesis of:Luminescent face-to-face dinuclear platinum(II) alkynyl phosphine silver(I) complexAlpha-diimine silver(I) complexesSilver(I) complexes with multidentate pyrazolyl-pyridine ligandsSilver(I) clusters with binding for a dithiophosphate ligand

Technology Process of TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE

There total 3 articles about TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

tetrafluoroboric acid + silver(l) oxide (20667-12-3) → tetrakis(acetonitrile)silver(I) tetrafluoroborate (93556-88-8)

Guidance literature:

With acetonitrile; In acetonitrile; 10 min; filtered, concd., Et2O was added, cooled to -20°C, recrystd. from acetonitrile-ether and dried in a stream of N2;

Reference yield: 68.0%

silver (7440-22-4) + nitrosonium tetrafluoroborate → tetrakis(acetonitrile)silver(I) tetrafluoroborate (93556-88-8)

Guidance literature:

In acetonitrile; byproducts: NO; N2; metallic silver added to suspn. of NOBF4; stirred for 0.5 h at 25-30°C, 0.5 h at 45-55°C, 15 min at 75-85°C; filtered; cooled to -5°C; filtered off; washed (dry ether); reprecipitated from mixt. of CH3CN and ether; elem.anal.;

Reference yield:

silver tetrafluoroborate (14104-20-2) + acetonitrile (75-05-8,26809-02-9) → tetrakis(acetonitrile)silver(I) tetrafluoroborate (93556-88-8)

Guidance literature:

In diethyl ether; acetonitrile; crystn.;

upstream raw materials:

silver

silver(l) oxide

silver tetrafluoroborate

acetonitrile

Downstream raw materials:

[(CO)3(((C₆H₅)2PCH₂)2)Mn(CCC(CH₃)3)]Ag[P(C₆H₄CH₃)3]⁽¹⁺⁾

Ag(Fe(C₅H₄SCH₃)(C₅H₄P(C₆H₅)2))2⁽¹⁺⁾*BF₄^(1-) = [Ag(Fe(C₅H₄SCH₃)(C₅H₄P(C₆H₅)2))2]BF₄

[Ag(NCMe)(HCCC₂)2Pt(1,2-bis(diphenylphosphino)ethane))]BF₄

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