Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

Base Information

Chemical Name:Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂
CAS No.:1206548-32-4
Molecular Formula:C₄₄H₃₂Cl₂N₄RuSe₄
Molecular Weight:1104.58
Hs Code.:

Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl<sub>2</sub>

Synonyms:Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

Suppliers and Price of Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

There total 2 articles about Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.4%

: 14898-67-0
ruthenium trichloride hydrate

: 1206548-28-8
6,6'-bis-phenylselenyl-2,2'-bipyridine

: 1206548-32-4
Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

Guidance literature:: With LiCl; In ethylene glycol; stirred under Ar at 150°C for 10 h; cooled to room temp., the ppt. washed (H2O), dried under vac. overnight,dissolved in MeOH, Et2O added slowly while stirring;
DOI:10.1021/ja9047027

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 49669-22-9
6,6'-Dibromo-2,2'-bipyridine

: 1206548-32-4
Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

Guidance literature:: Multi-step reaction with 2 steps

1: selenium; tert.-butyl lithium

2: lithium chloride; ethylene glycol

With selenium; tert.-butyl lithium; ethylene glycol; lithium chloride;
DOI:10.1002/ejic.201600123

Reference yield: 97.6%

: ammonium hexafluorophosphate

: hexafluorophosphoric acid

: 1206548-32-4
Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂

: 7732-18-5
water

: [Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2(H₂O)2](PF₆)2

Guidance literature:: In acetonitrile; Ru complex dissolved in MeCN under Ar, H2O added, heated at 60°C for 3 h; cooled to 0-5°C, HPF6 in H2O and NH4PH6 in H2O added, pptd. for 2h, collected, washed (HPF6 soln.), dried under vac. overnight; elem. an al.;
DOI:10.1021/ja9047027