Sulfur dichloride

Base Information

• Chemical Name: Sulfur dichloride
• CAS No.: 10545-99-0
• Deprecated CAS: 39461-36-4
• Molecular Formula: Cl2S
• Molecular Weight: 102.972
• Hs Code.: 28121042
• European Community (EC) Number: 234-129-0
• ICSC Number: 1661
• UN Number: 1828
• UNII: 8Q6684WQ9H
• DSSTox Substance ID: DTXSID4051538
• Nikkaji Number: J100.351H
• Wikipedia: Sulfur dichloride,Sulfur_dichloride
• Wikidata: Q409028
• Mol file: 10545-99-0.mol

Synonyms:SULFUR DICHLORIDE;Dichlorosulfane;10545-99-0;Sulphur dichloride;Sulfur chloride (SCl2);Chlorine sulfide;chloro thiohypochlorite;Monosulfur dichloride;Disulfur tetrachloride;Dichloro sulfide;UNII-8Q6684WQ9H;HSDB 798;8Q6684WQ9H;EINECS 234-129-0;EC 234-129-0;Sulphur chloride;chlorosulfenyl chloride;thiochloride;sulfenylchloride;sulfenyl chloride;sulphenyl chloride;Dichlorure de soufre;DICHLOROSULFUR;Cl2S;SCl2;Sulfur(II) dichloride;Sulfur (II) chloride;chlo-rosulfonium chloride;hypochlorous thioanhydride;Cl2-S;Chlorine sulfide (Cl2S);Sulfur dichloride (SCl2);Cloruro de azufre (SCl2);DTXSID4051538;SULFUR CHLORIDE (SCL2) [HSDB];LS-192791;5-tert-Butoxycarbonylamino-2-fluoroisonicotinicacid;Q409028

Chemical Property of Sulfur dichloride

Chemical Property:

• Appearance/Colour: Dark red or faint red liquid
• Vapor Pressure: 25.67 psi ( 55 °C)
• Melting Point: -78 °C
• Boiling Point: 59 °C
• PSA: 25.30000
• Density: 1.577 g/cm³
• LogP: 2.02720
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 101.9097766
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s): T, N, C
• Hazard Codes: T,N,C
• Statements: 23/24/25-34-40-50-37-14-35
• Safety Statements: 26-27-28-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Sulfur Compounds
• Canonical SMILES: S(Cl)Cl
• Inhalation Risk: A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
• Effects of Short Term Exposure: The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation may cause lung oedema.
• Uses: Chlorine carrier or chlorinating agent, rubber vulcanizing, vulcanized oils, purifying sugar juices, sulfur solvent, chloridizing agent in metallurgy, manufacture of organic chemicals and insecticides.

Technology Process of Sulfur dichloride

There total 71 articles about Sulfur dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

sulfur (7704-34-9) + diselenium dichloride (10025-68-0) → disulfur dichloride (10025-67-9) + sulfur selenium dichloride (1087399-32-3) + sulfur dichloride (10545-99-0) + selenium tetrachloride (10026-03-6)

Guidance literature:

In neat (no solvent); heating of equimolar amount in closed tube to 200°C for 6 h;; fractional distillation;;

Reference yield: 13.2%

disulfur dichloride (10025-67-9) + selenium (7782-49-2) → selenium sulfur dichloride + sulfur dichloride (10545-99-0) + selenium tetrachloride (10026-03-6)

Guidance literature:

In neat (no solvent); heating in closed tube to 200°C for 4 h;; fractional distillation;;

Reference yield: 1.58%

carbon disulfide (75-15-0,12122-00-8) → dichloromethanebis(sulphenyl chloride) (17494-65-4) + sulfur dichloride (10545-99-0) + chlorothio-trichloro-methane (594-42-3)

Guidance literature:

With chlorine; at -20 - -5 ℃; for 2.5h; Yields of byproduct given; Irradiation;

upstream raw materials:

carbon disulfide

chlorine

disulfur dichloride

sulfur trioxide

Downstream raw materials:

aluminium trichloride

sulfur dioxide

sulfur

cobalt(II) chloride

Refernces

• 1、 Emeleus,Miller. "". . p. 662. Retrieved 1966.
• 2、 Bothamley, R. P.. "". . p. 47. Retrieved 1928.
• 3、 DONOVAN RJ,HUSAIN D,JACKSON PT. "SPECTROSCOPIC AND KINETIC STUDIES OF THE SO RADICAL AND THE PHOTOLYSIS OF THIONYL CHLORIDE". . p. 2930 - 2940. Retrieved 1969.
• 4、 Finch, Arthur,Gates, Peter N.,Page, Terence H.,Dillon, Keith B.,Waddington, Thomas C.. "VIBRATIONAL AND CHLORINE-35 NUCLEAR QUADRUPOLE RESONANCE SPECTRA OF SOME COMPLEXES OF ICl4(-) AND AuCl4(-). PART 1. TWO CRYSTAL MODIFICATIONS OF TRICHLOROSULPHONIUM TETRACHLOROIODATE, ". . p. 2401 - 2404. Retrieved 1980.