p-nitrobenzyl hidroperoxide

Base Information

• Chemical Name: p-nitrobenzyl hidroperoxide
• CAS No.: 74127-43-8
• Molecular Formula: C₇H₇NO₄
• Molecular Weight: 169.137
• Mol file: 74127-43-8.mol

Synonyms:p-nitrobenzyl hidroperoxide

Chemical Property of p-nitrobenzyl hidroperoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-nitrobenzyl hidroperoxide

There total 4 articles about p-nitrobenzyl hidroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(p-nitrophenyl)-1-phenylethanol (20273-74-9) → benzaldehyde (100-52-7) + p-nitrobenzyl hidroperoxide (74127-43-8)

Guidance literature:

With oxygen; In water; acetonitrile; for 2h; Mechanism; Product distribution; Quantum yield; Irradiation; variation of pH (1-12);

DOI:10.1021/ja00221a038

Reference yield:

1-methyl-4-nitrobenzene (99-99-0) → 4-nitrobenzyl chloride (619-73-8) + p-nitrobenzyl hidroperoxide (74127-43-8) + 4-nitro-benzoic acid (62-23-7)

Guidance literature:

With N-hydroxyphthalimide; cobalt(II) 5,10,15,20-tetra(o-methoxyphenyl)porphyrin complex; oxygen; In neat (no solvent); at 120 ℃; for 8h; under 7500.75 Torr; Pressure; Reagent/catalyst; Autoclave;

DOI:10.1007/s10562-020-03214-y

Reference yield:

1-methyl-4-nitrobenzene (99-99-0) → 4-nitrobenzyl chloride (619-73-8) + 4-nitrobenzaldehdye (555-16-8) + p-nitrobenzyl hidroperoxide (74127-43-8) + 4-nitro-benzoic acid (62-23-7)

Guidance literature:

With N-hydroxyphthalimide; cobalt(II) 5,10,15,20-tetra(o-methoxyphenyl)porphyrin complex; oxygen; In neat (no solvent); at 120 ℃; under 7500.75 Torr; Reagent/catalyst; Temperature; Pressure; Catalytic behavior; Autoclave;

DOI:10.1007/s10562-020-03214-y

upstream raw materials:

2-(p-nitrophenyl)-1-phenylethanol

ascorbate

C₇H₆NO₄

1-methyl-4-nitrobenzene