20273-74-9

Usage

InChI:InChI=1/C14H13NO3/c16-14(12-4-2-1-3-5-12)10-11-6-8-13(9-7-11)15(17)18/h1-9,14,16H,10H2

Upstream product

• 3769-82-2 2-(4-nitrophenyl)-1-phenylethanone 
• 104-03-0 4-nitrobenzeneacetic acid 
• 100-52-7 benzaldehyde 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 3145-86-6 4-nitrobenzyl iodide 
• 114533-06-1 (4-nitrophenyl)methyl trifluoromethanesulfonate 
• 4450-68-4 4-nitrobenzyl tosylate 
• 39834-49-6 (((4-nitrobenzyl)oxy)methanetriyl)tribenzene 
• 619-90-9 4-nitrobenzyl acetate 
• 100-42-5 styrene 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 586-78-7 para-nitrophenyl bromide 
• 215254-67-4 2,2'-(1-phenylethane-1,2-diyl)dibenzo[1,3,2]dioxaborole 
• 71-43-2 benzene 

Downstream Products

• 106111-26-6 1-methoxy-2-(p-nitrophenyl)-1-phenylethane 
• 114423-73-3 1-acetoxy-2-(p-nitrophenyl)-1-phenylethane 
• 100-52-7 benzaldehyde 
• 62-23-7 4-nitro-benzoic acid 
• 74127-43-8 p-nitrobenzyl hidroperoxide 
• 736-30-1 1,2-bis(4-nitrophenyl)ethane 
• 99-99-0 1-methyl-4-nitrobenzene 

Relevant academic research and scientific papers

Heterogeneous visible-light-induced Meerwein hydration reaction of alkenes in water using mpg-C3N4 as a recyclable photocatalyst

A green and efficient visible light induced Meerwein hydration reaction of alkenes in aqueous medium using mpg-C3N4 as a recyclabe photocatalyst has been disclosed. This protocol provides a direct approach for the preparation of racemic alcohols via a free radical mechanism. Water acted as both a solvent and a reagent without any additives or co-solvents. The metal-free heterogeneous semiconductor is found to be fully recyclable at least 5 times without any significant reduction in activity. The Meerwein hydration reaction has an excellent substrate scope and gave the desired products in moderate to high yields. Furthermore, this reaction could be carried out under solar light irradiation and is applicable for large-scale reactions with satisfactory results.

Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts

The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical–polar crossover mechanism could be exten

Nickel-catalyzed reductive benzylation of aldehydes with benzyl halides and pseudohalides

The reductive benzylation of aromatic and aliphatic aldehydes with benzylic halides is reported using a nickel/zinc catalyst system. In addition to benzylic halides, the first report on the addition of benzylic triflates, acetates, tosylates and tritylates to aldehydes is also presented. By this new method a range of alcohols was synthesized efficiently from aldehydes and benzylic substrates at room temperature in moderate to high yields. The mild reaction conditions and good functional group tolerance make this nickel-catalyzed process synthetically useful for the synthesis of diverse benzylic alcohols.

Dinuclear ortho-metalated palladium(II) compounds with N,N- and N,O-donor bridging ligands. synthesis of new palladium(III) complexes

New dinuclear ortho-metalated palladium(II) compounds with N,N′-diarylformamidinates, Pd2[(C6H 4)PPh2]2[R′NC(H)NR′]2 (R′ = C6H5, 3a; R′ = p-CH3C 6/sub

Original reaction of p-nitrobenzyl chloride with aldehydes using tetrakis(dimethylamino)ethylene (TDAE)

A series of disubstituted diarylethanols was prepared in moderate to good yields by reaction of p-nitrobenzyl chloride (1) with various aromatic aldehydes (2-12) in presence of tetrakis(dimethylamino)ethylene (TDAE).

Sructure an Mechanism in the Photo-Retro-Aldol Type Reactions of Nitrobenzyl Derivatives. Photochemical Heterolytic Cleavage of C-C Bonds

The photo-retro-aldol type reactions of several nitroaromatic compounds have been studied in aqueous solution over the pH 1-14 range.These reactions are observed only in aqueous or in predominantly aqueous solution.Catalysis of reaction due to hydroxide ion is observed for several derivatives.Quantum yields of reaction and product ratios (of nitrotoluene vs dinitrobibenzyl) are reported as a function of pH.The proposed mechanism of reaction involves heterolytic cleavage of the benzylic C-C bond from the triplet excited state in the primary photochemical step to generate a nitrobenzyl carbanion and a carbocation-equivalent fragment, except for the nitrophenylacetates 24-26, which eliminate CO2 in place of such a fragment.Photogenerated nitrobenzyl carbanions are efficiently trapped by molecular oxygen to give isolable hydroperoxides at pH 9 M-1 s-1.The results show that photochemical C-C bond heterolysis requires favorable stabilization of both the carbanion and carbocation-derived fragments.Hydroxide ion catalysis may also facilitate the process.The use of the nitrobenzyl moiety as the carbanion-stabilizing group appears to be generally applicable, as demonstrated by the systems studied.