Cyclopropanecarboxylic acid, 2,2-diethoxy-, ethyl ester (9CI)

Base Information

Chemical Name:Cyclopropanecarboxylic acid, 2,2-diethoxy-, ethyl ester (9CI)
CAS No.:97149-57-0
Molecular Formula:C₁₀H₁₈O₄
Molecular Weight:202.251
Hs Code.:
Mol file:97149-57-0.mol

Synonyms:Cyclopropanecarboxylic acid, 2,2-diethoxy-, ethyl ester (9CI)

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Chemical Property of Cyclopropanecarboxylic acid, 2,2-diethoxy-, ethyl ester (9CI)

Chemical Property:

PSA：44.76000
LogP:1.33870

Purity/Quality:

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Technology Process of Cyclopropanecarboxylic acid, 2,2-diethoxy-, ethyl ester (9CI)

There total 2 articles about Cyclopropanecarboxylic acid, 2,2-diethoxy-, ethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 623-73-4
diazoacetic acid ethyl ester

: 2678-54-8
ketene diethyl acetal

: 97149-58-1
4,4-diethoxy-but-3-enoic acid ethyl ester

: 97149-57-0
2,2-Diethoxy-cyclopropanecarboxylic acid ethyl ester

Guidance literature:: copper acetylacetonate; In benzene; for 2.5h; Heating; Other catalyst: Cu powder;

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 2678-54-8
ketene diethyl acetal

: 97149-57-0
2,2-Diethoxy-cyclopropanecarboxylic acid ethyl ester

Guidance literature:: copper acetylacetonate; In benzene; at 85 ℃; for 0.333333h;
DOI:10.1055/s-1985-31338

Reference yield:

: 97149-57-0
2,2-Diethoxy-cyclopropanecarboxylic acid ethyl ester

: 124732-62-3,124732-63-4
ethyl cis-5-oxo-2-phenethyltetrahydrofuran-3-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) TiBr₄, 2.) p-TsOH / 1.) CH₂Cl₂, -78 deg C, 0.5 h, 2.) toluene, 80 deg C, 1 h

2: 68 percent / NaOEt / ethanol; tetrahydrofuran / 2 h / Ambient temperature

With sodium ethanolate; titanium(IV) bromide; toluene-4-sulfonic acid; In tetrahydrofuran; ethanol;
DOI:10.1021/jo00052a028