[bis(triphenylphosphine)iminium][(PhS)₂Fe(NO)₂]

Base Information

• Chemical Name: [bis(triphenylphosphine)iminium][(PhS)₂Fe(NO)₂]
• CAS No.: 769163-78-2
• Molecular Formula: C₁₂H₁₀FeN₂O₂S₂*C₃₆H₃₀NP₂
• Molecular Weight: 872.791
• Mol file: 769163-78-2.mol

Synonyms:[bis(triphenylphosphine)iminium][(PhS)₂Fe(NO)₂]

Chemical Property of [bis(triphenylphosphine)iminium][(PhS)₂Fe(NO)₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [bis(triphenylphosphine)iminium][(PhS)₂Fe(NO)₂]

There total 16 articles about [bis(triphenylphosphine)iminium][(PhS)₂Fe(NO)₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

{PPN}{SPh} (769163-80-6) + [bis(triphenylphosphoranylidene)ammonium][(nitrosyl)2Fe(SC7H4SN)2] → [bis(triphenylphosphine)iminium][(PhS)2Fe(NO)2] (769163-78-2)

Guidance literature:

In acetonitrile; under N2 atm. soln. Fe complex and (PPN)(SR) in MeCN was stirred for 5 min at room temp.; solvent was removed in vacuo, residue was dissolved in THF and filtered through Celite, hexane was added; elem. anal.;

DOI:10.1021/ic0505044

Reference yield: 93.0%

[PPN][Fe(SPh)3(NO)] + trityl thionitrite (6316-86-5) → [bis(triphenylphosphine)iminium][(PhS)2Fe(NO)2] (769163-78-2)

Guidance literature:

In dichloromethane; soln. Ph3CSNO in CH2Cl2 was added to soln. Fe complex in CH2Cl2 under N2atm. and stirred for 2 h at room temp.; hexane was added;

DOI:10.1021/ic061439g

Reference yield: 86.0%

{PPN}{SPh} (769163-80-6) + Roussin's Red ester → [bis(triphenylphosphine)iminium][(PhS)2Fe(NO)2] (769163-78-2)

Guidance literature:

In tetrahydrofuran; (N2 or Ar); a soln. of Fe complex added to ligand salt, stirred for 5 min at room temp.; filtered, concd., pptd. (Et2O, hexane);

DOI:10.1021/ic0605120

upstream raw materials:

{PPN}{SPh}

thiophenol

diphenyldisulfane

nitrogen(II) oxide

Downstream raw materials:

[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(S₅)]

ferrocene

diphenyldisulfane