[Fe₄S₄(benzenethiolate)4]^(2-)

Base Information

• Chemical Name: [Fe₄S₄(benzenethiolate)4]^(2-)
• CAS No.: 52325-39-0
• Molecular Formula: C₂₄H₂₀Fe₄S₈
• Molecular Weight: 788.339

Synonyms:[Fe₄S₄(benzenethiolate)4]^(2-)

Chemical Property of [Fe₄S₄(benzenethiolate)4]^(2-)

Chemical Property:

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Technology Process of [Fe₄S₄(benzenethiolate)4]^(2-)

There total 27 articles about [Fe₄S₄(benzenethiolate)4]^(2-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

{Fe4S4Cl4}(2-) + thiophenol (108-98-5) → [Fe4S4(benzenethiolate)4](2-) (52325-39-0)

Guidance literature:

With phenyllithium; diphenyldisulfane; In diethyl ether; the cluster added to a frozen soln. of PhLi in degassed ether, the mixt., after melting, stirred under atm. pressure of H2 at 0°C for 30min, addn. of benzenethiol and diphenyl disulphide;

DOI:10.1039/c39800000817

Reference yield: 82.0%

2N(C2H5)4(1+)*{NiFe3S4(P(C6H5)3)(SC2H5)3}(2-)={N(C2H5)4}2{NiFe3S4(P(C6H5)3)(SC2H5)3} + thiophenol (108-98-5) → [Fe4S4(benzenethiolate)4](2-) (52325-39-0) + {NiFe3S4(SC6H5)3(P(C6H5)3)}(2-)

Guidance literature:

In acetonitrile; byproducts: P(C6H5)3; under N2; monitored by (1)H-NMR;

Reference yield:

{Et4N}2{Fe4S4(SEt)4} + diphenyldisulfane (882-33-7) → Diethyl disulfide (110-81-6) + [Fe4S4(benzenethiolate)4](2-) (52325-39-0)

Guidance literature:

In dimethyl sulfoxide; for 36h;

DOI:10.1021/ic301324u

upstream raw materials:

tetraethylammonium phenylthiolate

thiophenol

iron(III)

thiophenolate

Downstream raw materials:

tetrakis[benzenethiolato-μ3-sulphido-iron](3-)

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