(CH₃)3CC(OZnC₂H₅)CHCH₃

Base Information

Chemical Name:(CH₃)3CC(OZnC₂H₅)CHCH₃
CAS No.:109930-68-9
Molecular Formula:C₉H₁₈OZn
Molecular Weight:207.631
Hs Code.:

(CH<sub>3</sub>)3CC(OZnC<sub>2</sub>H<sub>5</sub>)CHCH<sub>3</sub>

Synonyms:(CH₃)3CC(OZnC₂H₅)CHCH₃

Suppliers and Price of (CH₃)3CC(OZnC₂H₅)CHCH₃

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (CH₃)3CC(OZnC₂H₅)CHCH₃

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (CH₃)3CC(OZnC₂H₅)CHCH₃

There total 2 articles about (CH₃)3CC(OZnC₂H₅)CHCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109930-69-0
N-(ethylzinc) diisopropylamine

: 564-04-5
2,2-dimethyl-3-pentanone

: 109930-68-9
(CH₃)3CC(OZnC₂H₅)CHCH₃

: 108-18-9
diisopropylamine

Guidance literature:: In benzene-d6; equimolar quantities of starting materials, 45°C, 29 h, under N2; equil. reaction, t-BuC(OZnEt)=CHMe to t-BuC(O)Et ratio 1.2:1 ((1)H NMR data);
DOI:10.1021/om00153a006

Reference yield:

: 564-04-5
2,2-dimethyl-3-pentanone

: 1730-61-6
ethylzinc diphenylamide

: 109930-68-9
(CH₃)3CC(OZnC₂H₅)CHCH₃

: 122-39-4
diphenylamine

Guidance literature:: In benzene-d6; equimolar quantities of starting materials, room temp., 69 h, under N2; equil. reaction, t-BuC(OZnEt)=CHMe to t-BuC(O)Et ratio 1:1 ((1)H NMR data);
DOI:10.1021/om00153a006

Reference yield: 76.0%

: 109930-68-9
(CH₃)3CC(OZnC₂H₅)CHCH₃

: 538-44-3,28435-47-4,29569-91-3
(E)-benzylidenepinacolone

: 109960-03-4,123101-31-5,123101-32-6
anti-Me₃CC(=O)CHMeCHPhCH₂C(=O)CMe₃

Guidance literature:: In tetrahydrofuran; THF soln. of enone was added to a soln. of Zn-enolate in THF under N2, stirred for 5 h at 25°C; reaction mixt. before chromy. contained less than 5% of the syn Michael adduct ((1)H NMR data); aq. NH4Cl was added at 0°C, mixt. was partitioned between H2O and Et2O, aq. layer was washed with ether, org. layers were washed with brine, dried, evapd., chromd. on SiO2 (eluent ether-hexane); (1)H NMR and m.p. in agreement with those reported;
DOI:10.1021/om00153a006