3-benzylthiotriphenylamine

Base Information

• Chemical Name: 3-benzylthiotriphenylamine
• CAS No.: 406724-67-2
• Molecular Formula: C₂₅H₂₁NS
• Molecular Weight: 367.514
• Mol file: 406724-67-2.mol

Synonyms:3-benzylthiotriphenylamine

Chemical Property of 3-benzylthiotriphenylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-benzylthiotriphenylamine

There total 3 articles about 3-benzylthiotriphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.5%

benzyl-(3-bromophenyl)-sulfide (128133-75-5) + diphenylamine (122-39-4) → 3-benzylthiotriphenylamine (406724-67-2)

Guidance literature:

With 1,1'-bis(diphenylphosphino)ferrocene; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; sodium t-butanolate; In toluene; at 90 ℃; for 24h;

DOI:10.1021/ja011186k

Reference yield:

3-Bromothiophenol (6320-01-0) → 3-benzylthiotriphenylamine (406724-67-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium methoxide / methanol / 0.5 h / 20 °C

1.2: 85.5 percent / methanol / 20 °C

2.1: 62.5 percent / Pd₂(dba)3; bis(diphenylphosphino)ferrocene; sodium tert-butoxide / toluene / 24 h / 90 °C

With 1,1'-bis(diphenylphosphino)ferrocene; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; sodium methylate; sodium t-butanolate; In methanol; toluene;

DOI:10.1021/ja011186k

Reference yield:

benzyl bromide (100-39-0) → 3-benzylthiotriphenylamine (406724-67-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium methoxide / methanol / 0.5 h / 20 °C

1.2: 85.5 percent / methanol / 20 °C

2.1: 62.5 percent / Pd₂(dba)3; bis(diphenylphosphino)ferrocene; sodium tert-butoxide / toluene / 24 h / 90 °C

With 1,1'-bis(diphenylphosphino)ferrocene; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; sodium methylate; sodium t-butanolate; In methanol; toluene;

DOI:10.1021/ja011186k

upstream raw materials:

benzyl-(3-bromophenyl)-sulfide

diphenylamine

3-Bromothiophenol

benzyl bromide