Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester

Base Information

• Chemical Name: Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester
• CAS No.: 78687-53-3
• Molecular Formula: C₁₂H₁₇NO₅Si
• Molecular Weight: 283.356
• Mol file: 78687-53-3.mol

Synonyms:Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester

Chemical Property of Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester

There total 1 articles about Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.7%

meta-nitrophenol (554-84-7) + 2-(trimethylsilyl)-ethoxycarbonyl chloride (20160-60-5) → Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester (78687-53-3)

Guidance literature:

In pyridine; at 20 ℃; for 0.5h;

DOI:10.1016/0040-4039(81)89023-5

Reference yield: 90.0%

Carbonic acid 3-nitro-phenyl ester 2-trimethylsilanyl-ethyl ester (78687-53-3) → ethene (74-85-1) + trimethylsilyl fluoride (420-56-4) + meta-nitrophenol (554-84-7)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 0.166667h; deprotection of TMSEC derivat with various catalyst;

DOI:10.1016/0040-4039(81)89023-5

upstream raw materials:

meta-nitrophenol

2-(trimethylsilyl)-ethoxycarbonyl chloride

Downstream raw materials:

ethene

trimethylsilyl fluoride

meta-nitrophenol