benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside

Base Information

Chemical Name:benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside
CAS No.:1382060-13-0
Molecular Formula:C₂₂H₃₈O₆Si
Molecular Weight:426.626
Hs Code.:

Synonyms:benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside

Chemical Property:

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Technology Process of benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside

There total 1 articles about benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: benzyl 6-O-tert-butyldimethylsilyl-α-D-mannopyranoside

: 74-88-4
methyl iodide

: 1382060-13-0
benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside

Guidance literature:: benzyl 6-O-tert-butyldimethylsilyl-α-D-mannopyranoside; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.5h; Inert atmosphere;

methyl iodide; In N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1021/ol3013638

Reference yield: 93.0%

: 1382060-13-0
benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside

: 1382060-15-2
benzyl 2,3,4-tri-O-methyl-α-D-mannopyranoside

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; for 6h; Inert atmosphere;
DOI:10.1021/ol3013638

Reference yield:

: 1382060-13-0
benzyl 6-O-(tert-butyldimethyl)silyl-2,3,4-tri-O-methyl-α-D-mannopyranoside

: 1382060-16-3
benzyl 2,3,4-tri-O-methyl-α-D-mannopyranosidurononitrile

Guidance literature:: Multi-step reaction with 4 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 6 h / 0 - 20 °C / Inert atmosphere

2: Dess-Martin periodane / dichloromethane / 2 h / 20 °C

3: pyridine; hydroxylamine hydrochloride / methanol; water / 2 h / 20 °C

4: pyridine; methanesulfonyl chloride / 2 h / 0 - 20 °C / Inert atmosphere

With pyridine; hydroxylamine hydrochloride; tetrabutyl ammonium fluoride; Dess-Martin periodane; methanesulfonyl chloride; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/ol3013638