Technology Process of C19H30O2Si
There total 4 articles about C19H30O2Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
phenylacetylene;
With
n-butyllithium;
In
tetrahydrofuran;
at -78 ℃;
for 1h;
Inert atmosphere;
5-tert-butyldimethylsilyloxypentanal;
In
tetrahydrofuran;
at -78 - 20 ℃;
Inert atmosphere;
DOI:10.1039/c1ob06138k
- Guidance literature:
-
Multi-step reaction with 2 steps
1: pyridinium chlorochromate / 20 °C
2: n-butyllithium / tetrahydrofuran / 0.25 h / 20 °C
With
n-butyllithium; pyridinium chlorochromate;
In
tetrahydrofuran;
DOI:10.1002/anie.201203923
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium hydride / tetrahydrofuran; mineral oil / 2.5 h / 0 - 23 °C / Inert atmosphere
1.2: 12 h / 23 °C / Inert atmosphere
2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; potassium bromide; sodium hypochlorite solution / dichloromethane; water / 0.25 h / 0 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.42 h / -78 - 23 °C / Inert atmosphere
With
n-butyllithium; sodium hypochlorite solution; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydride; sodium hydrogencarbonate; potassium bromide;
In
tetrahydrofuran; hexane; dichloromethane; water; mineral oil;
DOI:10.1021/ja408957a
