Methyl 4,6-di-O-methyl-2-O-(phenylmethyl)-alpha-D-mannopyranoside

Base Information

Chemical Name:Methyl 4,6-di-O-methyl-2-O-(phenylmethyl)-alpha-D-mannopyranoside
CAS No.:366801-82-3
Molecular Formula:C₁₆H₂₄O₆
Molecular Weight:312.363
Hs Code.:
DSSTox Substance ID:DTXSID801180015

Synonyms:DTXSID801180015;Methyl 4,6-di-O-methyl-2-O-(phenylmethyl)-alpha-D-mannopyranoside;366801-82-3

Suppliers and Price of Methyl 4,6-di-O-methyl-2-O-(phenylmethyl)-alpha-D-mannopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl 4,6-di-O-methyl-2-O-(phenylmethyl)-alpha-D-mannopyranoside

Chemical Property:

XLogP3:0.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:7
Exact Mass:312.15728848
Heavy Atom Count:22
Complexity:307

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COCC1C(C(C(C(O1)OC)OCC2=CC=CC=C2)O)OC
Isomeric SMILES:COC[C@@H]1[C@H]([C@@H]([C@@H]([C@H](O1)OC)OCC2=CC=CC=C2)O)OC

Technology Process of Methyl 4,6-di-O-methyl-2-O-(phenylmethyl)-alpha-D-mannopyranoside

There total 1 articles about Methyl 4,6-di-O-methyl-2-O-(phenylmethyl)-alpha-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 100-39-0
benzyl bromide

: 4153-25-7,13000-41-4,23262-68-2,23487-00-5,25029-39-4,35780-76-8,52554-55-9,82262-93-9
Methyl 4,6-di-O-methyl-α-D-mannopyranoside

: 150161-24-3
Methyl 3-O-benzyl-4,6-di-O-methyl-α-D-mannopyranoside

: 366801-82-3
methyl 2-O-benzyl-4,6-di-O-methyl-α-D-mannopyranoside

Guidance literature:: With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; water; for 168000h; Heating;
DOI:10.1021/jo0101860

Reference yield: 100.0%

: 623-68-7
trans-crotonic anhydride

: 366801-82-3
methyl 2-O-benzyl-4,6-di-O-methyl-α-D-mannopyranoside

: 366801-85-6
methyl 2-O-benzyl-3-O-crotonyl-4,6-di-O-methyl-α-D-mannopyranoside

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 16h;
DOI:10.1021/jo0101860

Reference yield:

: 366801-82-3
methyl 2-O-benzyl-4,6-di-O-methyl-α-D-mannopyranoside

: (S)-3-Methyl-pent-4-enoic acid (2S,3S,4S,5R,6R)-3-benzyloxy-2,5-dimethoxy-6-methoxymethyl-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 100 percent / Et₃N; 4-dimethylaminopyridine / CH₂Cl₂ / 16 h

2.1: CuBr*Me₂S / tetrahydrofuran; various solvent(s) / 1 h / -78 °C

2.2: tetrahydrofuran; various solvent(s) / -78 °C

With dmap; copper(I) bromide dimethylsulfide complex; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo0101860