2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

Base Information

Chemical Name:2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride
CAS No.:201600-44-4
Molecular Formula:C₃₄H₃₃ClFeP₂
Molecular Weight:594.884
Hs Code.:

Synonyms:2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

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Chemical Property of 2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

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Technology Process of 2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

There total 2 articles about 2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: iron(II) chloride

: 201600-44-4
2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

Guidance literature:: With n-BuLi; MeC(CH₂PPh₂)2CH₂C₅H₅; In tetrahydrofuran; hexane; Ar-atmosphere; stirring ligand (in THF) with equimolar amt. of BuLi (in hexane) at 0°C for 0.5 h, dropwise addn. to equimolar amt. of FeCl2 suspn. (in THF), stirring (room temp., 2 h); evapn. (vac.), dissoln. in Et2O/CH2Cl2=4:1, filtration (SiO2), evapn., crystn. on Et2O diffusion into CH2Cl2 soln. for 5 d; elem. anal.;
DOI:10.1016/S0022-328X(97)00502-0

Reference yield: 52.0%

: 7705-08-0
iron(III) chloride

: 201600-44-4
2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

Guidance literature:: With PhLi; MeC(CH₂PPh₂)2CH₂C₅H₅; n-BuLi; In tetrahydrofuran; Ar-atmosphere; stirring ligand (in THF) with equimolar amt. of BuLi (in hexane) at 0°C for 0.5 h, dropwise addn. to equimolar amt. of FeCl3 suspn. (in THF), stirring (room temp., 2 h), addn. of PhLi (in cyclohexane/Et2O), stirring for 1 h; evapn., dissoln. in Et2O/CH2Cl2=4:1, filtration (SiO2), evapn.;
DOI:10.1016/S0022-328X(97)00502-0

Reference yield: 75.0%

: sodium hexaflorophosphate

: 201600-44-4
2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

: 75-05-8,26809-02-9
acetonitrile

: 201600-51-3
(acetonitrile)-(2,2-bis(diphenylphosphinomethyl))-(η(5)-cyclopentadienylpropyl)iron(II) hexafluorophosphate

Guidance literature:: In acetonitrile; Ar-atmosphere; addn. of equimolar amt. of NaPF6 to Fe-complex soln., stirring (room temp., 8 h); evapn., dissoln. in CH2Cl2, filtration (SiO2), evapn. (vac.); elem. anal.;
DOI:10.1016/S0022-328X(97)00502-0