2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(III) chloride hexafluorophosphate

Base Information

Chemical Name:2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(III) chloride hexafluorophosphate
CAS No.:201600-48-8
Molecular Formula:C₃₄H₃₃ClFeP₂*F₆P
Molecular Weight:739.848
Hs Code.:

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Chemical Property of 2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(III) chloride hexafluorophosphate

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Technology Process of 2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(III) chloride hexafluorophosphate

There total 2 articles about 2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(III) chloride hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 201600-44-4
2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(II) chloride

: 437-17-2
tritylium hexafluorophosphate

: 201600-48-8
2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(III) chloride hexafluorophosphate

Guidance literature:: In dichloromethane; Ar-atmosphere; slow addn. of equimolar amt. of Ph3CPF6 to Fe-complex soln. at -70°C; slow warming to room temp. with stirring over 2 h, evapn., dissoln. in CH2Cl2/THF=3:1, filtration (SiO2), evapn.;
DOI:10.1016/S0022-328X(97)00502-0

Reference yield: 64.0%

: sodium hexaflorophosphate

: 7705-08-0
iron(III) chloride

: 201600-48-8
2,2-bis(diphenylphosphinomethyl)-(η(5)-cyclopentadienylpropyl)iron(III) chloride hexafluorophosphate

Guidance literature:: With n-BuLi; MeC(CH₂PPh₂)2CH₂C₅H₅; In tetrahydrofuran; Ar-atmosphere; stirring ligand with equimolar amt. of BuLi at 0°Cfor 0.5 h, dropwise addn. to equimolar amt. of FeCl3 soln., stirring (r oom temp., 3 h), evapn., dissoln. in CH2Cl2/THF, filtration, dissoln. inEtOH, addn. of NaPF6, stirring 0.5 h; evapn. (vac.), dissoln. in CH2Cl2, filtration (SiO2), evapn.; elem. anal.;
DOI:10.1016/S0022-328X(97)00502-0