(3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

Base Information

Chemical Name:(3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde
CAS No.:14260-64-1
Molecular Formula:C₈H₁₀O₄
Molecular Weight:170.165
Hs Code.:

(3a<i>R</i>)-2,2-dimethyl-(3a<i>r</i>,6a<i>c</i>)-3a,6a-dihydro-furo[2,3-<i>d</i>][1,3]dioxole-5-carbaldehyde

Synonyms:(3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

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Chemical Property of (3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

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Technology Process of (3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

There total 2 articles about (3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 23558-05-6
3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose

: 138430-42-9
3-O-benzyl-6-deoxy-6,6,6-trifluoro-1,2-O-isopropylidene-α-D-glucofuranose

: 204315-89-9
3-O-benzyl-6-deoxy-6,6,6-trifluoro-1,2-O-isopropylidene-β-L-idofuranose

: 14260-64-1
(3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

Guidance literature:: With iodotrifluoromethane; zinc; In N,N-dimethyl-formamide; Yields of byproduct given; ultrasound irradiation;
DOI:10.1248/cpb.39.2459

Reference yield: 20.0%

: 2314-97-8,263005-66-9
iodotrifluoromethane

: 23558-05-6
3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose

: 138430-42-9
3-O-benzyl-6-deoxy-6,6,6-trifluoro-1,2-O-isopropylidene-α-D-glucofuranose

: 204315-89-9
3-O-benzyl-6-deoxy-6,6,6-trifluoro-1,2-O-isopropylidene-β-L-idofuranose

: 14260-64-1
(3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

Guidance literature:: With zinc; In N,N-dimethyl-formamide; Yield given. Yields of byproduct given; ultrasound irradiation;
DOI:10.1248/cpb.39.2459

Reference yield: 85.0%

: 103535-06-4
(2-(benzyloxy)ethyl)triphenylphosphonium bromide

: 14260-64-1
(3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

: C₁₇H₂₀O₄

Guidance literature:: (2-(benzyloxy)ethyl)triphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; for 0.5h; Cooling with ethanol-dry ice;

(3aR)-2,2-dimethyl-(3ar,6ac)-3a,6a-dihydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde; In tetrahydrofuran; at 20 ℃; for 1.16667h;