iron(II)β-diketiminate complex

Base Information

• Chemical Name: iron(II)β-diketiminate complex
• CAS No.: 887001-74-3
• Molecular Formula: C₃₃H₅₂FeN₂Si
• Molecular Weight: 560.722

Synonyms:iron(II)β-diketiminate complex

Chemical Property of iron(II)β-diketiminate complex

Chemical Property:

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Technology Process of iron(II)β-diketiminate complex

There total 4 articles about iron(II)β-diketiminate complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

iron(dichloride)*1.5(tetrahydrofuran) + trimethylsilylmethyllithium (1822-00-0) + 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene → iron(II)β-diketiminate complex (887001-74-3)

Guidance literature:

2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;

iron(dichloride)*1.5(tetrahydrofuran); In tetrahydrofuran; hexane; for 0.75h; Inert atmosphere; Schlenk technique; Glovebox;

trimethylsilylmethyllithium; In tetrahydrofuran; hexane; for 0.75h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/chem.201503399

Reference yield: 58.0%

iron(dichloride)*1.5(tetrahydrofuran) + C30H44N2 + trimethylsilylmethyllithium (1822-00-0) → iron(II)β-diketiminate complex (887001-74-3)

Guidance literature:

C₃₀H₄₄N₂; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.5h; Schlenk technique; Inert atmosphere;

iron(dichloride)*1.5(tetrahydrofuran); In tetrahydrofuran; hexane; for 0.75h; Schlenk technique; Inert atmosphere;

trimethylsilylmethyllithium; In tetrahydrofuran; hexane; for 0.5h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.202004980

Reference yield: 27.0%

iron(II) chloride*1.5THF + trimethylsilylmethyllithium (1822-00-0) + 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene (289618-59-3) → iron(II)β-diketiminate complex (887001-74-3)

Guidance literature:

With CH₃(CH₂)3Li; In tetrahydrofuran; hexane; (under N2, Schlenk); CH3(CH2)3Li in hexane added to stirred soln. of ligand in THF, stirred for 30 min at room temp., FeCl2(C4H8O)1.5 added, stirred for 45 min, LiCH2Si(CH3)3 added, stirred for 45 min; THF evapd. under reduced pressure, stirred in pentane, evapd., extd. with pentane, concd., cooled at -25°C; elem. anal.;

DOI:10.1016/j.ica.2005.06.065

upstream raw materials:

trimethylsilylmethyllithium

2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene

2,6-diisopropylbenzenamine

acetylacetone

Downstream raw materials:

HC(C(CH₃)N(CH(CH₃)2)2C₆H₃)2Fe(C₄⁽²⁾H₈O)⁽¹⁺⁾*B(C₆F₅)4^(1-)=HC(C(CH₃)N(CH(CH₃)2)2C₆H₃)2Fe(C₄⁽²⁾H₈O)B(C₆F₅)4

5-(trimethylsilyl)pent-1-ene

(((C₃H₇)2C₆H₃NCCH₃)2CH)FeCl₂

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