N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide

Base Information

Chemical Name:N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide
CAS No.:144002-79-9
Molecular Formula:C₄₇H₆₄N₂O₆Si
Molecular Weight:781.12
Hs Code.:

Synonyms:N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide

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Chemical Property of N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide

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Technology Process of N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide

There total 4 articles about N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 40615-36-9
4,4'-dimethoxytrityl chloride

: 144002-78-8
N-<6-(tert-butyldimethylsiloxy)hexyl>-N'-(6-hydroxyhexyl)terephthalamide

: 144002-79-9
N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide

Guidance literature:: With pyridine; dmap;
DOI:10.1021/ja00049a003

Reference yield:

: 4048-33-3
6-amino-1-hexanol

: 144002-79-9
N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide

Guidance literature:: Multi-step reaction with 4 steps

1: 11.2 g / imidazole / dimethylformamide / Ambient temperature

2: 0.704 g / K₂CO₃ / benzene; diethyl ether; H₂O

3: 40 percent / Bu₄NF / tetrahydrofuran / 1 h

4: 65 percent / pyridine, 4-(dimethylamino)pyridine

With pyridine; 1H-imidazole; dmap; tetrabutyl ammonium fluoride; potassium carbonate; In tetrahydrofuran; diethyl ether; water; N,N-dimethyl-formamide; benzene;
DOI:10.1021/ja00049a003

Reference yield:

: 124883-99-4
6-((tert-butyldimethylsilyl)oxy)hexan-1-amine

: 144002-79-9
N'-<6-(tert-butyldimethylsiloxy)hexyl>-N-<(6-(4,4'-dimethoxytrityl)oxy)hexyl>terephthalamide

Guidance literature:: Multi-step reaction with 3 steps

1: 0.704 g / K₂CO₃ / benzene; diethyl ether; H₂O

2: 40 percent / Bu₄NF / tetrahydrofuran / 1 h

3: 65 percent / pyridine, 4-(dimethylamino)pyridine

With pyridine; dmap; tetrabutyl ammonium fluoride; potassium carbonate; In tetrahydrofuran; diethyl ether; water; benzene;
DOI:10.1021/ja00049a003